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Morphotropism of Rare-Earth Orthoborates RBO3

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Abstract

A diagram in the coordinates “temperature-ionic radius” is built for polymorphic and morphotropic transitions in a series of REE orthoborates. The stability fields are determined for the structural types of calcite, aragonite, vaterite, pseudo-vaterite, H-LaBO3, and L-SmBO3. The temperatures of some metastable phase transformations are estimated.

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References

  1. N. I. Leonyuk and L. I. Leonyuk. Crystal Chemistry of Anhydrous Borates [in Russian]. Izdatelstvo MGU: Moskva, 1983.

    Google Scholar 

  2. R. S. Bubnova and S. K. Filatov. High-Temperature Crystal Chemistry of Borates and Borosilicates [in Russian]. Nauka: Moskva, 2008.

    Google Scholar 

  3. A. E. Kokh, N. G. Kononova, T. B. Bekker et al. Russian J. Inorg. Chem, 2004, 49, 984.

    Google Scholar 

  4. N. G. Furmanova, B. A. Maksimov, V. N. Molchanov et al. Crystallogr. Rep., 2006, 51, 219.

    Article  CAS  Google Scholar 

  5. E. L. Belokoneva, A. G. Ivanova, O. V. Dmitrieva et al. Zh. Neorg. Khim., 2006, 51, 939 [in Russian].

    CAS  Google Scholar 

  6. T. B. Bekker, S. V. Rashchenko, Y. V. Seryotkin, and P. P. Fedorov. J. Amer. Ceram. Soc., 2018, 101, 450.

    Article  CAS  Google Scholar 

  7. C. Chen, T. Sasaki, R. Li et al. Nonlinear Optical Borate Crystals. Viley-VCH: Weinheim, 2012.

    Book  Google Scholar 

  8. P. P. Fedorov, A. E. Kokh, and N. G. Kononova. Russian Chem. Rev., 2002, 71, 651.

    Article  CAS  Google Scholar 

  9. A. V. Egorysheva and V. M. Skorikov. Inorg. Mater., 2009, 45, 1461.

    Article  CAS  Google Scholar 

  10. T. B. Bekker, P. P. Fedorov, and A. E. Kokh. Phase Formation and Crystal Growth in the Quadruple Reciprocal System Na, Ba, B // O, F [in Russian]. Izdatelstvo SO RAN: Novosibirsk, 2016.

    Google Scholar 

  11. N. I. Leonyuk, V. V. Maltsev. Single Crystals of Refractory Borates [in Russian]. GEOS: Moskva, 2016.

    Google Scholar 

  12. P. Wang, J. M. Dawes, P. Dekker, and J. A. Piper. Opt. Comm., 2000, 174, 467.

    Article  CAS  Google Scholar 

  13. X. Long, X. Lin, Z. Hu et al. J. Alloys Compd., 2002, 347, 52.

    Article  CAS  Google Scholar 

  14. G. Corbel, R. Retoux, and M. Leblanc. J. Solid State Chem., 1998, 139, 52.

    Article  CAS  Google Scholar 

  15. Y. M. Andreev, A. E. Kokh, K. A. Kokh et al. Opt. Mater., 2017, 66, 94.

    Article  CAS  Google Scholar 

  16. W. W. Moses, M. J. Weber, S. E. Derenzo, P. Berdah. In: Proc. Int. Conf. Inorg. Scintillators and Their Applications, 1997, 22–25.

  17. P. A. Rodnyi. Radiat. Meas., 2001, 33, 605.

    Article  CAS  Google Scholar 

  18. A. W. Veenis and A. Bril. Philips J. Res., 1978, 33, 124.

    CAS  Google Scholar 

  19. X. C. Jiang, C. H. Yan, L. D. Sun, Z. G. Wei, and C. S. Liao. J. Solid State Chem., 2003, 175, 251.

    Article  CAS  Google Scholar 

  20. J. Fan, Z. Lin, L. Zhang, and G. Wang. J. Phys. D. Appl. Phys., 2006, 39, 3226.

    Article  CAS  Google Scholar 

  21. D. Lu, Z. Pan, Y. Haohai et al. Opt. Mater. Express, 2015, 5, 1822.

    Article  CAS  Google Scholar 

  22. P. P. Fedorov. Crystallogr. Rep., 1995, 40, 278.

    Google Scholar 

  23. P. P. Fedorov and B. P. Sobolev. Crystallogr. Rep., 1995, 40, 284.

    Google Scholar 

  24. P. P. Fedorov, M. V. Nazarkin, and R. M. Zakalyukin. Crystallogr. Rep., 2002, 47, 281.

    Article  CAS  Google Scholar 

  25. V. M. Goldschmidt and H. Hauptmann. Nach. Ges. Wiss. Gott. Math-Phys. Kl., 1932, 53.

  26. E. M. Levin, R. S. Roth, and J. B. Martin. Amer. Miner., 1961, 46, 1030.

    CAS  Google Scholar 

  27. R. S. Roth, J. L. Waring, E. M. Levin. In: Rare Earth Research II. Proc. 3rd Conf. Rare Earth Research, 1963, 153.

  28. E. M. Levin. In: E. M. Levin, C. R. Robbins, H. F. McMurdie. Phase Diagrams for Ceramists. Amer. Ceram. Soc.: Columbus, 1987.

    Google Scholar 

  29. D. A. Keszler and H. Sun. Acta Cryst., 1988, C44, 1505.

    CAS  Google Scholar 

  30. J. R. Cox and D. A. Keszler. Acta Cryst., 1994, C50, 1857.

    CAS  Google Scholar 

  31. S. C. Abrahams, J. L. Bernstein, and E. T. Keve. J. Appl. Cryst., 1971, 4, 284.

    Article  CAS  Google Scholar 

  32. E. J. Felten. J. Inorg. Nucl. Chem., 1961, 19, 61.

    Article  CAS  Google Scholar 

  33. R. E. Newnham, M. J. Redman, and R. P. Santoro. J. Amer. Ceram. Soc., 1963, 46, 253.

    Article  CAS  Google Scholar 

  34. W. F. Bradley and D. L. Graf, R. S. Roth. Acta Cryst., 1966, 20, 283.

    Article  CAS  Google Scholar 

  35. P. E. D. Morgan., P. J. Carrol, and F. F. Lange. Mat. Res. Bull., 1977, 12, 251.

    Article  CAS  Google Scholar 

  36. G. Chadeyron, M. El-Ghozzi, R. Mahiou et al. J. Solid State Chem., 1997, 128, 261.

    Article  CAS  Google Scholar 

  37. M. Ren, J. H. Lin, Y. Dong et al. Chem. Mater., 1999, 11, 1576.

    Article  CAS  Google Scholar 

  38. G. Chadeyron, R. Mahiou, M. El-Ghozzi et al. J. Lumin., 1997, 564, 72.

    Google Scholar 

  39. M. Th. Cohen-Adad, O. Aloui-Lebbou, C. Goutandier et al. J. Solid State Chem., 2000, 154, 204.

    Article  CAS  Google Scholar 

  40. J. Lin, D. Sheptyakov, Y. Wang, and P. Allenspach. Chem. Mater., 2004, 16, 2418.

    Article  CAS  Google Scholar 

  41. J. H. Denning and S. D. Ross. Spectrochim. Acta, 1972, A28, 1775.

    Article  Google Scholar 

  42. H. M. Kriz and P. J. Bray. J. Chem. Phys., 1969, 51, 3624.

    Article  CAS  Google Scholar 

  43. J. Weidelt, H. U. Bambauer. Naturwissenschaften, 1968, 55, 342.

    Article  CAS  Google Scholar 

  44. H. J. Meyer. Naturwissenschaften, 1969, 56, 458.

    Article  CAS  Google Scholar 

  45. E. Antic-Fidancev, J. Aride, J.-P. Chaminade, M. Lemaitre-Blaise, and P. Porcher. J. Solid State Chem., 1992, 97, 74.

    Article  CAS  Google Scholar 

  46. R. Boehlhoff, H. U. Bambauer, and W. Hoffmann. Z. Krist., 1971, 133, 386.

    Article  CAS  Google Scholar 

  47. H. J. Meyer and A. Skokan. Naturwissenschaften, 1971, 58, 566.

    Article  CAS  Google Scholar 

  48. H. J. Meyer. Naturwissenschaften, 1972, 59, 215.

    Article  CAS  Google Scholar 

  49. K. K. Palkina, V. G. Kuznetsov, L. A. Bytman, and B. F. Dzhyrinskii. Coord. Khim., 1976, 2, 286 [in Russian].

    CAS  Google Scholar 

  50. G. Corbel, M. Leblanc, E. Antic-Fidancev, M. Lemaitre-Blaise, and J. C. Krupa. J. Alloys Comp., 1999, 287, 71.

    Article  CAS  Google Scholar 

  51. M. Yin, G. Corbel, M. Leblanc, E. Antic-Fidancev, and J. C. Krupa. J. Alloys Comp., 2000, 302, 12.

    Article  CAS  Google Scholar 

  52. H. Huppertz, B. Von der Eltz, D. Hoffmann, and H. Piotrowski. J. Solid State Chem., 2002, 166, 203.

    Article  CAS  Google Scholar 

  53. M. Levin. J. Amer. Ceram. Soc., 1967, 50, 53.

    Article  CAS  Google Scholar 

  54. E. A. Tkachenko, P. P. Fedorov, S. V. Kuznetsov et al. Inorg. Mater., 2006, 42, 171.

    Article  CAS  Google Scholar 

  55. J. Plewa and T. Justel. J. Thermal Anal. Calorim., 2007, 88, 531.

    Article  CAS  Google Scholar 

  56. B. M. Wanklin. J. Mater. Sci., 1973, 8, 1055.

    Article  Google Scholar 

  57. V. M. Fedorova, N. G. Kononova, A. E. Kokh, and V. S. Shevchenko. Neorgan. Mater., 2013, 49, 505 [in Russian].

    Google Scholar 

  58. A. V. Nikolaev. Physical and Chemical Investigation of Natural Borates [in Russian]. Izdatelstvo AN SSSR: Moskva-Leningrad, 1947.

    Google Scholar 

  59. E. M. Shvarts and A. E. Dzene. In: Borates and Borate Systems [in Russian]. Ed. G. Ya. Slaydin. Zinatne: Riga, 1978, 101.

  60. R. D. Shannon. Acta Cryst. A, 1976, 32, 751.

    Article  Google Scholar 

  61. P. P. Fedorov and B. P. Sobolev. Zh. Fiz. Khim., 1988, 62, 896 [in Russian].

    CAS  Google Scholar 

  62. J. Holsa. Inorg. Chem. Acta, 1987, 139, 257.

    Article  CAS  Google Scholar 

  63. D. Boyer, F. Leroux, G. Bertrand, and R. Mahiou. J. Non-Cryst. Sol., 2002, 306, 110.

    Article  CAS  Google Scholar 

  64. Y. T. Wu, D. Z. Ding, S. K. Pan, F. Yang, and G. H. Ren. Phase Transitions, 2011, 84, 315.

    Article  CAS  Google Scholar 

  65. Y. Wu, D. Ding, F. Yang, S. Pan, and G. Ren. Mater. Res. Bull., 2012, 47, 106.

    Article  CAS  Google Scholar 

  66. D. Yoshimura, S. Tatsuya, and H. Yukio. J. Solid State Chem., 2013, 206, 151.

    Article  CAS  Google Scholar 

  67. P. P. Fedorov. Dokl. Phys., 2016, 61, 427.

    Article  CAS  Google Scholar 

  68. E. A. Tkachenko, P. P. Fedorov, S. V. Kuznetsov et al. Russ. J. Inorg. Chem., 2005, 50, 681.

    Google Scholar 

  69. N. G. Kononova, A. E. Kokh, T. B. Bekker et al. Inorg. Mater., 2004, 40, 1208.

    Article  CAS  Google Scholar 

  70. J. Weidelt. Z. Anorg. Allg. Chem., 1970, 374, 26.

    Article  CAS  Google Scholar 

  71. H. Huppertz. Z. Naturforsch. B, 2001, 56, 697.

    Article  CAS  Google Scholar 

  72. S. Lemanceau, G. Bertrand-Chadeyron, R. Mahiou, M. El-Ghozzi, J. C. Cousseins, P. Conflant, and R. N. Vannier. J. Solid State Chem., 1999, 148, 229.

    Article  CAS  Google Scholar 

  73. G. Bertrand-Chadeyron, M. El-Ghozzi, D. Boyer, R. Mahiou, J. C. Cousseins. J. Alloys Compd., 2001, 317–318, 183.

    Article  Google Scholar 

  74. E. A. Tkachenko, R. Mahiou, G. Chadeyron et al. Russ. J. Inorg. Chem, 2007, 52, 829.

    Article  Google Scholar 

  75. JCPDS card № 12-0762.

  76. JCPDS card № 24-1272.

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  1. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, Russia

    P. P. Fedorov

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  1. P. P. Fedorov
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Correspondence to P. P. Fedorov.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 5, pp. 713-725.

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Fedorov, P.P. Morphotropism of Rare-Earth Orthoborates RBO3. J Struct Chem 60, 679–691 (2019). https://doi.org/10.1134/S0022476619050019

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