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An Unprecedented Trinuclear Nickel(II) Complex Assembled from an Asymmetric Salamo-Type Ligand

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Abstract

An unprecedented trinuclear Ni(II) complex assembled from an asymmetric Salamo-type ligand 6-ethoxy- 4′,6′-dichloro-2,2′-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol (H2L) is synthesized. The Ni(II) complex with the general formula [Ni3(L)2(μ3-OAc)2]·3CH3CN is characterized by IR, UV-vis, and fluorescence spectra and the single crystal X-ray analysis. All the Ni(II) atoms are hexacoordinated with slightly distorted octahedral symmetries. Interestingly, each Ni(II) atom is not located on the N2O2 cavity of the asymmetric Salamo-type (L)2– unit, and two μ3-OAc ions adopt an uncommon μ3-η2:η1 binding mode connecting the Ni1, Ni2, and Ni3 atoms. Furthermore, the crystallizing acetonitrile molecules successfully assemble into an infinite 2D network by hydrogen bonding and C–H···π interactions.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, P.R. China

    Y. Zhang, L.-Z. Liu, L. Gao, S.-F. Akogun & W.-K. Dong

Authors
  1. Y. Zhang
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  2. L.-Z. Liu
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  3. L. Gao
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  4. S.-F. Akogun
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  5. W.-K. Dong
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Corresponding author

Correspondence to W.-K. Dong.

Additional information

Original Russian Text © 2018 Y. Zhang, L.-Z. Liu, L. Gao, S.-F. Akogun, W.-K. Dong.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 7, pp. 1723–1731, September-October, 2018.

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Zhang, Y., Liu, LZ., Gao, L. et al. An Unprecedented Trinuclear Nickel(II) Complex Assembled from an Asymmetric Salamo-Type Ligand. J Struct Chem 59, 1664–1673 (2018). https://doi.org/10.1134/S002247661807020X

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  • DOI: https://doi.org/10.1134/S002247661807020X

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