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Ionic Mobility in Pb0.9M0.1F2.1 (M = Bi, In) and Pb0.9Bi0.05In0.05F2.1 Solid Solutions with the Fluorite-Type Structure According NMR Data

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Abstract

Ionic mobility in solid solutions Pb0.9Bi0.1F2.1, Pb0.9In0.1F2.1, and Pb0.9Bi0.05In0.05F2.1 with the fluorite structure is studied with the 19F NMR method at 150–470 K. Temperature regions associated with local motions in the fluoride sublattice of these solid solutions are determined. The ratio of “fixed” (in the NMR scale) and mobile fluoride ions in the transition region (200-300 K) depends on the temperature, concentration of MF3 fluorides, and the nature of M3+ cations. Translational diffusion of fluoride ions is the predominant ionic motion in solid solutions above 300 K to cause high ionic conductivity in the samples.

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References

  1. A. K. Ivanov-Schits and I. V. Murin. Solid State Ionics. [in Russian] Vol. 1. St. Petersburg University Publ., St. Petersburg, 2000. Vol. 2. St. Petersburg University Publ., St. Petersburg, 2010.

    Google Scholar 

  2. M. A. Reddy and M. Fichtner. J. Mater. Chem., 2011, 21, 17059–17062.

    Article  CAS  Google Scholar 

  3. V. Trnovcová, P. P. Fedorov, and I. Furar. Russ. J. Electrochem., 2009, 45, 630–639.

    Article  CAS  Google Scholar 

  4. P. Berastegui and S. Hull. Solid State Ion., 2002, 154-155, 605–608.

    Article  CAS  Google Scholar 

  5. J. M. Réau and P. Hagenmuller. Rev. Inorg. Chem., 1999, 19, 45–77.

    Article  Google Scholar 

  6. Y. Ito, K. Koto, S. Yoshikado, and T. Ohachi. Solid State Ion., 1986, 18-19(Part 2), 1202–1207.

    Article  CAS  Google Scholar 

  7. I. I. Buchinskaya and P. P. Fedorov. Russ. Chem. Rev., 2004, 73, 371–400.

    Article  CAS  Google Scholar 

  8. S. Hull, P. Berastegui, S. G. Eriksson, and N. J. G. Gardner. J. Phys.: Condens. Matter, 1998, 10, 8429–8446.

    CAS  Google Scholar 

  9. V. Ya. Kavun, V. K. Goncharuk, A. B. Slobodyuk, and L. N. Alekseiko. Solid solutions and glasses based on lead(II) and bismuth(III) fluorides [in Russian]. Vladivostok. The Far East. Fed. un-ty. 2013.

    Google Scholar 

  10. V. M. Buznik, A. A. Sukhovskii, V. A. Vopilov, et al. Russ. J. Inorg. Chem., 1997, 42, 2092–2097.

    CAS  Google Scholar 

  11. P. Darbon, J.-M. Réau, and P. Hagenmuller. Mater. Res. Bull., 1981, 16, 273–277.

    Article  CAS  Google Scholar 

  12. V. Ya. Kavun, A. B. Slobodyuk, S. L. Sinebryukhov, et al. Russ. J. Electrochem., 2007, 43, 611–624.

    Article  CAS  Google Scholar 

  13. S. Hull and P. Berastegui. J. Phys.: Condens. Matter, 1999, 11, 5257–5272.

    CAS  Google Scholar 

  14. M. Wahbi, J. M. Réau, and J. Sénégas. Phys. Stat. Sol. (a) Appl. Res., 1991, 125, 517–527.

    Article  CAS  Google Scholar 

  15. S. P. Gabuda, Yu. V. Gagarinskiy, and S. A. Polishchuk. NMR in the Inorganic Fluorides [in Russian], Atomizdat Moscow, 1978.

    Google Scholar 

  16. A. G. Lundin and E. I. Fedin. NMR Spectroscopy [in Russian]. Nauka, Moscow, 1986.

    Google Scholar 

  17. V. Ya. Kavun, A. B. Slobodyuk, E. A. Tararako, et al. Inorg. Mater., 2005, 41, 1228–1235.

    Article  CAS  Google Scholar 

  18. V. Ya. Kavun, A. B. Slobodyuk, S. V. Gnedenkov, et al. J. Struct. Chem., 2007, 48, 840–847.

    Article  CAS  Google Scholar 

  19. S. K. Soo, J. Senegas, J. M. Réau, et al. J. Solid State Chem., 1993, 104, 215–225.

    Article  CAS  Google Scholar 

  20. P. Laborde, G. Villeneuve, J. M. Réau, and P. Hagenmuller. Z. Anorg. Allg. Chem., 1986, 537, 40–52.

    Article  CAS  Google Scholar 

  21. K. Suh, J. Sénégas, J. M. Réau, and P. Hagenmuller. J. Solid State Chem., 1991, 93, 469–484.

    Article  CAS  Google Scholar 

  22. Malika El Omari, E. Hafidi, M. El Omari, et al. Mater. Lett., 2002, 53, 138–144.

    Article  Google Scholar 

  23. V. Ya. Kavun, N. F. Uvarov, A. B. Slobodyuk, et al. J. Solid State Chem., 2017, 249, 204–209.

    Article  CAS  Google Scholar 

  24. M. El Omari, J. Sénégas, and J. M. Réau. Solid State Ion., 1997, 100, 233–240.

    Article  Google Scholar 

  25. M. El Omari, J. Sénégas, and J. M. Réau. Solid State Ion., 1997, 100, 241–246.

    Article  Google Scholar 

  26. M. El Omari, J. L. Soubeyroux, J. M. Réau, and J. Sénégas. Solid State Ion., 2000, 130, 133–141.

    Article  Google Scholar 

  27. S. K. Soo, J. Sénégas, J. M. Réau, et al. J. Solid State Chem., 1992, 97, 212–223.

    Article  CAS  Google Scholar 

  28. A. Lucat, J. M. Rhandour, J. M. Réau, et al. J. Solid State Chem., 1979, 29, 373–377.

    Article  CAS  Google Scholar 

  29. M. Kumar, K. Yamada, T. Okuda, and S. S. Sekhon. Phys. Stat. Sol. (b), 2003, 239, 432–438.

    Article  CAS  Google Scholar 

  30. A. Abragam. The principles of nuclear magnetism. Clarendon press, Oxford, 1961.

    Google Scholar 

  31. H. S. Gutowsky and G. E. Pake. J. Chem. Phys., 1950, 18, 162–170.

    Article  CAS  Google Scholar 

  32. J. M. Réau, S. Matar, S. Kacim, et al. Solid State Ion., 1982, 7, 165–170.

    Article  Google Scholar 

  33. M. Wahbi, J. M. Réau, and J. Sénégas. Mater. Lett., 1992, 13, 218–224.

    Article  CAS  Google Scholar 

  34. E. F. Hairetdinov, N. F. Uvarov, J.M. Réau, et al. Solid State Ion., 1994, 73, 93–98.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia

    V. Ya. Kavun, E. B. Merkulov, A. B. Slobodyuk, M. M. Polyantsev & O. V. Brovkina

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  1. V. Ya. Kavun
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  2. E. B. Merkulov
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  3. A. B. Slobodyuk
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  4. M. M. Polyantsev
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  5. O. V. Brovkina
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Correspondence to V. Ya. Kavun.

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Original Russian Text © 2018 V. Ya. Kavun, E. B. Merkulov, A. B. Slobodyuk, M. M. Polyantsev, O. V. Brovkina.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 7, pp. 1632–1639, September-October, 2018.

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Kavun, V.Y., Merkulov, E.B., Slobodyuk, A.B. et al. Ionic Mobility in Pb0.9M0.1F2.1 (M = Bi, In) and Pb0.9Bi0.05In0.05F2.1 Solid Solutions with the Fluorite-Type Structure According NMR Data. J Struct Chem 59, 1572–1579 (2018). https://doi.org/10.1134/S0022476618070089

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