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Study of Acidic (Tetracaprolactam) Dodecamolybdosilicate of the Composition (C6H11NO)4.5Н4[SiМо12O40]

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Abstract

New caprolactam dodecamolybdosilicate of the composition (C6H11NO)4.5Н4[SiМо12O40] (I) is synthesized. Chemical and crystallographic analyses, NMR and IR spectroscopic studies are performed. Compound I is found to crystallize in the monoclinic system with the space group P21/n. Unit cell parameters are: a = 19.945(4) Å, b = 13.340(3) Å, c = 28.110(6) Å, β = 110.75(3)°, ρcalc = 2.232 g/cm3, М = 2350.63, Z = 4, V = 6994(3) Å3.

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Authors and Affiliations

  1. Moscow Pedagogical State University, Moscow, Russia

    A. F. Stepnova, G. Z. Kaziev & Nguen Van Bang

  2. National Research Center “Kurchatov Institute”, Moscow, Russia

    P. V. Dorovatovskii & Ya. V. Zubavichus

  3. Universidad autónoma metropolitana, Azcapotzalco, México

    Saúl Holguín Quiñones

  4. Russian University of Peoples Friendship, Moscow, Russia

    V. N. Khrustalev

Authors
  1. A. F. Stepnova
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  2. G. Z. Kaziev
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  3. P. V. Dorovatovskii
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  4. Ya. V. Zubavichus
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  5. Saúl Holguín Quiñones
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  6. Nguen Van Bang
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  7. V. N. Khrustalev
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Corresponding author

Correspondence to A. F. Stepnova.

Additional information

Original Russian Text © 2018 A. F. Stepnova, G. Z. Kaziev, P. V. Dorovatovskii, Ya. V. Zubavichus, Saúl Holguín Quiñones, Nguen Van Bang, V. N. Khrustalev.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 649–656, March-April, 2018.

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Stepnova, A.F., Kaziev, G.Z., Dorovatovskii, P.V. et al. Study of Acidic (Tetracaprolactam) Dodecamolybdosilicate of the Composition (C6H11NO)4.5Н4[SiМо12O40]. J Struct Chem 59, 627–634 (2018). https://doi.org/10.1134/S0022476618030174

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  • DOI: https://doi.org/10.1134/S0022476618030174

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