Abstract
The crystallographic analysis of the structure of three inorganic compounds with Lindqvist polyanions establishes that their structural arrangement is determined by the geometry and symmetry of the [M6] cation octahedron by the coherent assembly of [M6O19] building blocks. The relative stability of the structures is estimated from the number of degrees of freedom of their atoms and the fundamental volumes characterizing the degree of symmetrization of the structures.
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Original Russian Text © 2018 S. V. Borisov, S. A. Magarill, N. V. Pervukhina.
Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 635–639, March-April, 2018.
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Borisov, S.V., Magarill, S.A. & Pervukhina, N.V. Crystallographic Analysis of Compounds with Lindqvist Polyanions: Coherent Assembly, Symmetry, Stability. J Struct Chem 59, 612–617 (2018). https://doi.org/10.1134/S0022476618030150
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DOI: https://doi.org/10.1134/S0022476618030150