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Structure and Magnetic Properties of a New Lattice System of the Heterometallic Decanuclear Ce6Mn4 Aggregate

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Abstract

In this paper, we present a mixed valence f–d Ce6Mn III4 compound having formula [Ce IV6 Mn III4 (μ4-O)4 (μ3-O)4(O2CtBu)12(ea)4(OAc)4]·H2O (1), which is obtained by the reaction of hydrated lanthanide nitrate, pivalic acid, and ethanolamine in MeCN as a solvent. The single crystal X-ray diffraction analysis demonstrates that the central core consists of an octahedron with four triangular pyramids added to four related faces or as an octahedron encapsulated in a tetragon. The fitting of magnetization data using the anisotropic model gives D = 2.13 cm–1 and g = 1.97 (D is the axial zero-field splitting parameter).

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Agriculture, Faisalabad, Pakistan

    M. N. Akhtar

  2. Department of Chemistry, Faculty of Science, the University of Jordan, Amman, Jordan

    M. A. AlDamen

  3. Department of Chemistry, Abdul Wali Khan University, Mardan, Pakistan

    M. Ikram

  4. School of Chemistry, University of Manchester, Manchester, UK

    S. Ali

Authors
  1. M. N. Akhtar
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  2. M. A. AlDamen
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  3. M. Ikram
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  4. S. Ali
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Corresponding author

Correspondence to M. A. AlDamen.

Additional information

Original Russian Text © 2018 M. N. Akhtar, M. A. AlDamen, M. Ikram, S. Ali.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 607–611, March-April, 2018.

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Akhtar, M.N., AlDamen, M.A., Ikram, M. et al. Structure and Magnetic Properties of a New Lattice System of the Heterometallic Decanuclear Ce6Mn4 Aggregate. J Struct Chem 59, 584–588 (2018). https://doi.org/10.1134/S0022476618030113

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  • DOI: https://doi.org/10.1134/S0022476618030113

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