Abstract
A series of Ni- and/or Cu-containing coatings formed by plasma electrolytic oxidation on aluminum and titanium are examined by X-ray photoelectron spectroscopy. Binding energies of core electrons, elemental composition, chemical state of elements, and features of the structural organization of the surface and nearsurface layers of the coatings are determined. A combination of the data collected indicates similar regularities of the composition and significant distinctions in the structure of the coatings formed. It is shown that the coatings formed on titanium are characterized by a considerably higher phosphorus concentration, and correspondingly, phosphates, unlike the coatings formed on aluminum, in which base metal and 3d element (Ni or Cu) oxides are dominant. In both cases, Cu is mainly concentrated in the surface layers of the coatings whereas Ni is mainly concentrated in the near-surface layers.
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P. Kurze, J. Schreckenbach, T. H. Schwarz, and W. Krysmann, Metalloberflaeche, 40, No. 12, 539 (1986).
V. V. Bakovets, O. V. Polyakov, and I. P. Dolgovesova, Plasma Electrolytic Anodic Treatment of Metals [in Russian], Nauka, Novosibirsk (1991).
P. S. Gordienko, Formation of Coatings on Anode Polarized Electrodes in Aqueous Electrolytes at Sparking and Breakdown Potentials [in Russian]. Dal’nauka, Vladivostok (1996).
V. I. Belevantsev, O. P. Terleeva, G. A. Markov, E. K. Shulepko, A. I. Slonova, and V. V. Utkin, Prot. Met. Phys. Chem. Surf., 34, No. 5, 416 (1998).
A. L. Yerokhin, X. Nie, A. Leyland, A. Matthews, and S. J. Dowey, Surf. Coat. Technol., 122, No. 2/3, 73 (1999).
F. C. Walsh, C. T. J. Low, R. J. K. Wood, K. T. Stevens, J. Archer, A. R. Poeton, and A. Ryder, Trans. Inst. Met. Finish., 87, No. 3, 122 (2009).
A. I. Mamaev, Yu. Yu. Chekanova, and Zh. M. Ramazanova, Fiz. Khim. Obrab. Mater., No. 4, 41 (1999).
S. V. Gnedenkov, S. L. Sinebryukhov, and V. I. Sergienko, Composite Multifunctional Coatings on Metals and Alloys Formed by Plasma Electrolytic Oxidation [in Russian], Dal’nauka, Vladivostok (2013).
V. S. Rudnev, N. B. Kondrikov, L. M. Tyrina, D. L. Boguta, M. S. Vasilieva, and I. V. Lukiyanchuk, Ser. Kriticheskie tekhnologii. Membrany, 28, No. 4, 63 (2005).
I. V. Lukiyanchuk, L. M. Tyrina, and V. S. Rudnev, Prot. Met. Phys. Chem. Surf., 45, No. 5, 580 (2009).
S. V. Gnedenkov, Yu. P. Sharkeev, S. L. Sinebryukhov, O. A. Khrisanfova, E. V. Legostaeva, A. G. Zavidnaya, A. V. Puz’, and I. A. Khlusov, Tikhookeanskii Meditsinskii Zhurnal, No. 1, 12 (2012).
V. S. Rudnev, I. V. Lukiyanchuk, M. S. Vasilyeva, M. A. Medkov, M. V. Adigamova, and V. I. Sergienko, Surf. Coat. Technol., 307, Part C, 1219 (2016).
V. S. Rudnev, A. Yu. Ustinov, I. V. Lukiyanchuk, I. A. Tkachenko, V. P. Morozova, P. V. Kharitonskii, and A. M. Frolov, Prot. Met. Phys. Chem. Surf., 46, No. 5, 566 (2010).
V. S. Rudnev, I. V. Lukiyanchuk, and V. G. Kuryavyi, Prot. Met. Phys. Chem. Surf., 45, No. 1, 71 (2009).
V. S. Rudnev, I. V. Lukiyanchuk, L. M. Tyrina, S. Wybornova, T. Staedler, and M. S. Vasil'eva, Prot. Met. Phys. Chem. Surf., 45, No. 6, 709 (2009).
V. S. Rudnev, P. S. Gordienko, A. G. Kurnosova, and T. I. Orlova, Microarc Oxidation of Valve Metals and Their Alloys [in Russian], Pat. 1783004 USSR, MPK S 25 D 11/02.–N 4757905; claimed 17.10.1989; published 23.12.1992, Bull. No.47.
V. S. Rudnev, L. M. Tyrina, A. Y. Ustinov, I. V. Lukiyanchuk, and S. Vybornova, Kinet. Catal., 51, No. 2, 266 (2010).
J. F. Moulder, W. F. Stickle, P. E. Sobol, and K. D. Bomben, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corp., Minnesota (1992).
V. S. Rudnev and V. P. Morozova, Protection of Metals and Physical Chemistry of Surfaces, 44, No. 5, 506 (2008).
W. T. A. Harrison, T. E. Gier, and G. D. Stucky, Acta Crystallogr. Sect. C, C50, 1643 (1994).
I. V. Lukiyanchuk, V. S. Rudnev, T. A. Kaidalova, A. S. Rudnev, and P. S. Gordienko, Russ. J. Appl. Chem., 73, No. 6, 982 (2000).
N. S. McIntyre, S. Sunder, D. W. Shoesmith, and F. W. Stanchell, J. Vac. Sci. Technol., 18, No. 3, 714 (1981).
N. S. McIntyre and M. G. Cook, Analyt. Chem., 47, No. 13, 2208 (1975).
B. R. Strohmeier, D. E. Leyden, R. S. Field, and D. M. Hercules, J. Catal., 94, No. 2, 514 (1985).
J. C. Klein, C. P. Li, D. M. Hercules, and J. F. Black, Appl. Spectrosc., 38, No. 5, 729 (1984).
E. A. Koblova, A. Yu. Ustinov, I. V. Chernykh, I. V. Lukiyanchuk, and V. S. Rudnev, Izv. Yugo-Zapad. Univers., Ser. Tekhn. Tekhnol., 18, No. 1, 130 (2016).
E. A. Koblova, A. Yu. Ustinov, I. V. Chernykh, I. V. Lukiyanchuk, and V. S. Rudnev, Vestn. DVO RAN, No. 4, 39 (2015).
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Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 6, pp. 1175–1183, July–August, 2017.
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Koblova, E.A., Ustinov, A.Y., Rudnev, V.S. et al. An X-ray photoelectron spectroscopy study of Ni, Cu-containing coatings formed by plasma electrolytic oxidation on aluminum and titanium. J Struct Chem 58, 1129–1136 (2017). https://doi.org/10.1134/S0022476617060099
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DOI: https://doi.org/10.1134/S0022476617060099