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Stabilization of Ferromagnetism in BiFeO3:Ho at Hydrostatic Pressure

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Abstract

The isothermal magnetization of the Bi1 – xHo x FeO3 (x = 0−0.2) multiferroic has been studied at a hydrostatic pressure up to 9 GPa in the range of room temperatures. A new anomaly at PC ≈ 3.81 GPa related to intermediate phases between the structural transition R3cPnma has been found against the background of the pressure-induced antiferromagnetic ordering in BiFeO3 (BFO) at P ≈ 2.59 GPa. It is established that the ferromagnetic behavior under pressure depends on the Ho impurity concentration: PC decreases at 0.05 ≤ x ≤ 0.1 because of the decrease in R3c bond lengths in the structure, and the stabilization of ferromagnetism is implemented at 0.1 ≤ x ≤ 0.2 probably because of the coexistence of the R3c and Pnma phases. The results of studies indicate that, in Bi1 – xHo x FeO3 with x = 0.2, the transition pressure PC = 3.7 GPa exceeds the values for BFO doped with other 4f elements (Eu, Y, Sm) in the region R3cPnma of the transition.

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Correspondence to T. R. Arslanov.

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Original Russian Text © T.R. Arslanov, S.N. Kallaev, L.A. Reznichenko, 2018, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2018, Vol. 107, No. 8, pp. 499–504.

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Arslanov, T.R., Kallaev, S.N. & Reznichenko, L.A. Stabilization of Ferromagnetism in BiFeO3:Ho at Hydrostatic Pressure. Jetp Lett. 107, 477–482 (2018). https://doi.org/10.1134/S0021364018080088

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