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Chemiluminescent Method for Determination of Rate Constants for Reactions of Triplet Aromatic Nitrenes

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Abstract

It has been shown that the chemiluminescence accompanying the deoxygenation of nitrosobenzenes with triphenylphosphine can be used to measure the rate constants of reactions of the intermediates triplet nitrenes with the system components nitroso compounds and triphenylphosphine.

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Correspondence to V. A. Shamukaev.

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Original Russian Text © V.A. Shamukaev, E.M. Chainikova, A.M. Idrisova, R.L. Safiullin, 2018, published in Khimiya Vysokikh Energii, 2018, Vol. 52, No. 2, pp. 109–115.

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Shamukaev, V.A., Chainikova, E.M., Idrisova, A.M. et al. Chemiluminescent Method for Determination of Rate Constants for Reactions of Triplet Aromatic Nitrenes. High Energy Chem 52, 123–130 (2018). https://doi.org/10.1134/S0018143918020133

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  • DOI: https://doi.org/10.1134/S0018143918020133

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