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High Energy Chemistry

, Volume 52, Issue 2, pp 123–130 | Cite as

Chemiluminescent Method for Determination of Rate Constants for Reactions of Triplet Aromatic Nitrenes

  • V. A. Shamukaev
  • E. M. Chainikova
  • A. M. Idrisova
  • R. L. Safiullin
Photonics
  • 18 Downloads

Abstract

It has been shown that the chemiluminescence accompanying the deoxygenation of nitrosobenzenes with triphenylphosphine can be used to measure the rate constants of reactions of the intermediates triplet nitrenes with the system components nitroso compounds and triphenylphosphine.

Keywords

chemiluminescence aromatic nitroso compounds nitrene triphenylphosphine rate constants 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. A. Shamukaev
    • 1
  • E. M. Chainikova
    • 1
  • A. M. Idrisova
    • 2
  • R. L. Safiullin
    • 1
  1. 1.Ufa Institute of ChemistryRussian Academy of SciencesUfa, BashkortostanRussia
  2. 2.Bashkir State Pedagogical UniversityUfa, BashkortostanRussia

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