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Geochemistry International

, Volume 57, Issue 6, pp 716–721 | Cite as

Natural Kaersutite: FTIR, Raman, Thermal, and Thermochemical Studies

  • L. P. Ogorodova
  • Yu. D. Gritsenko
  • M. F. Vigasina
  • L. V. MelchakovaEmail author
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Abstract

The paper reports original thermochemical data obtained on natural oxo-amphibole kaersutite Na0.4K0.3(Ca1.6Na0.4)(Mg2.9\({\text{Fe}}_{{0.8}}^{{2 + }}\)Al0.7Ti0.6\({\text{Fe}}_{{0.5}}^{{3 + }}\))[Si6.1Al1.9O22](OH)0.2O1.8 from alkaline basalt in Mongolia. The data were obtained using a Tian–Calvet microcalorimeter. The enthalpy of formation from elements Δf\(H_{{{\text{el}}}}^{{\text{0}}}\)(298.15 K) = –12102 ± 16 kJ/mol) was obtained by high-temperature melt solution calorimetry. The entropy, enthalpy, and Gibbs energy of formation of the end members of the isomorphic series kaersutite NaCa2Mg3TiAl[Si6Al2O22]O2–ferrikaersutite NaCa2Mg3TiFe3+[Si6Al2O22]O2 were estimated.

Keywords:

thermochemistry Calvet microcalorimetry the enthalpy of formation kaersutite ferrikaersutite 

Notes

ACKNOWLEDGMENTS

The authors thank Prof. E.M. Spiridonov, Geological Faculty, Lomonosov Moscow State University) for providing a kaersutite sample for this study.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • L. P. Ogorodova
    • 1
  • Yu. D. Gritsenko
    • 1
  • M. F. Vigasina
    • 1
  • L. V. Melchakova
    • 1
    Email author
  1. 1.Geological Faculty, Moscow State UniversityMoscowRussia

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