Skip to main content
Log in

Soils as a Possible Source of Fluorine in the Atmosphere

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

A hypothesis was proposed that a considerable amount of gaseous HF is supplied to the atmosphere from the soil cover owing to the reaction \({{{\text{H}}}^{ + }} + {{{\text{F}}}^{ - }} = {\text{HF}}{\text{.}}\) In the upper layer of tundra and taiga soils with pH 4.0–4.5, the partial pressure of HF is (65–20) × 10–12 atm. Correspondingly, the concentration of dissolved F in the condensates of water vapor is 1.6–11 μg/L, which is comparable with F concentration in rainwater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. J. M. Bewers and H. H. Haysom, “The terrigenous dust contribution to fluoride and iodide in atmospheric precipitation,” J. Rech. Atmos. 8, 689–697 (1974).

    Google Scholar 

  2. T. K. Goryshina, Ecology of Plants (Vysshaya Shkola, Moscow 1979) [in Russian].

    Google Scholar 

  3. S. P. Khromov and M. A. Petrosyants, Meteorology and Climatology (MGU, Moscow, 2004) [in Russian].

  4. G. B. Naumov, B. N. Ryzhenko, and I. L. Khodakovsky, Handbook of Thermodynamic Data (Atomizdat, Moscow, 1971) [in Russian]. V. S. Savenko, “Fluorine genesis in atmospheric precipitates,” Dokl. Akad. Nauk SSSR 231 (2), 463–466.

  5. S. L. Shvartsev, Hydrogeochemistry of the Supergene Zone (Nedra, Moscow, 1998) [in Russian].

    Google Scholar 

  6. Soil Science. Part 2. Soil Types, Geography, and Use, Ed. By V.A. Kovda and B.G. Rozanov (Vysshaya Shkola, Moscow, 1988) [in Russian].

    Google Scholar 

Download references

ACKNOWLEDGMENTS

The research was supported by RFBR (project № 18-05-01133).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. S. Savenko.

Additional information

Translated by A. Girnis

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Savenko, V.S. Soils as a Possible Source of Fluorine in the Atmosphere. Geochem. Int. 56, 961–962 (2018). https://doi.org/10.1134/S0016702918090094

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702918090094

Keywords:

Navigation