Skip to main content
SpringerLink
Log in

Nonequilibrium Thermodynamics and Stoichiography in Studying Solid-Phase Processes of Fabrication of Functional Materials

  • PHYSICAL CHEMISTRY
  • Published:
Doklady Physical Chemistry Aims and scope Submit manuscript

Abstract

The application of general principles of nonequilibrium thermodynamics and stoichiography allows obtaining novel information on the solid-phase transformations of multielement and heterophase substances and materials. Without solid-phase standards, the use of stoichiography makes it possible to detect, identify, and quantify known and unknown crystalline and amorphous phases of constant or variable composition. For the first time, reliable results are presented concerning the evolution of solid products in the course of preparation of the Mo–V–Te–Nb–O catalyst of propane ammoxidation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Prigogine, I, and Defay, R., Chemical Thermodynamics, London: Longman Green, 1954. Translated under the title Khimicheskaya termodinamika, Moscow: Binom, 2009.

  2. Bazhin, I.M. and Parmon, V.N., Termodinamika dlya khimikov (Thermodynamics for Chemists), Mowcow: Khimiya KoloS, 2004.

  3. Parmon, V.N., Termodinamika neravnovesnykh pro-tsessov dlya khimikov (Thermodynamisc of Nonequilibrium Processes for Chemists), Dolgoprudnyi: Intellekt, 2015.

  4. Parmon, V.N., Dokl. Phys. Chem., 2013, vol. 452, part 1, pp. 200–204.

    Article  CAS  Google Scholar 

  5. Slin’ko, M.G., Osnovy i printsipy matematicheskogo modelirovaniya kataliticheskikh protsessov (Foundations and Principles of Mathematical Modeling of Catalytic Processes), Novosibirsk: Institut kataliza im. G.K. Boreskova SO RAN, 2004.

  6. Malakhov, V.V. and Vasil’eva, I.G., Usp. Khim., 2008, vol. 77, no. 4. pp. 370–392.

    Article  Google Scholar 

  7. Malakhov, V.V., Stekhiografiya, ili osnovnye nachala iskusstva obnaruzheniya, identifikatsii i kolichestvennogo opredeleniya khimicheskikh soedinenii bez ispol’zovaniya ikh etalonov (Stoichiography, or Foundations of the Art of Detection, Identification, and Quantification of Chemical Compounds without Using Their Standards), Novosibirsk: Izd. SO RAN, 2018.

  8. Tret’yakov, Yu.D., Usp. Khim., 2003, vol. 72, no. 8, p. 731.

    Google Scholar 

  9. Malakhov, V.V., Zh. Anal. Khim., 2017, vol. 72, no. 6, pp. 1–15.

    Google Scholar 

  10. Popova, G.Ya., Andrushkevich, T.V., Dovlitova, L.S., Aleshina, G.I., Chesalov, Ya., Ishenko, A.V., Ishenko, E.V., Plyasova, L.M., Malakhov, V.V., and Khramov, M.I., Appl. Catal. A, Gen., 2009, vol. 353, pp. 249–257.

    Article  CAS  Google Scholar 

  11. Characterization of Solid Materials and Heterogeneous Catalysts, Che, M. and Védrine, J.C., Eds., Wiley-VCH, 2012, vols. 1 and 2.

    Google Scholar 

Download references

ACKNOWLEDGMENTS

We express our gratitude to our colleagues, coauthors of the article [10], and above all, to Dr. T.V. Andrushkevich for initiating and conducting comprehensive studies of the Mo–V–Te–Nb–O catalyst system, including stoichiography methods, for useful discussions and support.

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. V. Malakhov &  V. N. Parmon

Authors
  1. V. V. Malakhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Parmon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Malakhov.

Additional information

Translated by G. Kirakosyan

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Malakhov, V.V., Parmon, V.N. Nonequilibrium Thermodynamics and Stoichiography in Studying Solid-Phase Processes of Fabrication of Functional Materials. Dokl Phys Chem 488, 138–141 (2019). https://doi.org/10.1134/S0012501619090070

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012501619090070

Search

Navigation