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Dependence of the properties of fluorine-containing poly(phenylquinoxaline) on the method of its preparation

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Abstract

A method of synthesis of new fluorine-containing tetraamine, 2,2-bis[4-(3,4-diaminophenoxy) phenyl]hexafluoropropane, has been developed; the tetraamine has been used as the initial compound for preparing poly(phenylquinoxaline)s in both supercritical carbon dioxide and solution. Thermal characteristics of fluorine-containing poly(phenylquinoxaline)s have been studied. There is a bimodal particle size distribution at the used polymer concentration (C pol = 0.1 wt %) according to dynamic laser light scattering data.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    N. M. Belomoima, E. G. Bulycheva, L. N. Nikitin, M. I. Buzin & I. S. Chashchin

  2. Demidov Yaroslavl’ State University, Yaroslavl’, 150000, Russia

    R. S. Begunov & A. I. Khlopotinin

  3. Emanuel’ Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    L. A. Vasserman

Authors
  1. N. M. Belomoima
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  2. E. G. Bulycheva
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  3. R. S. Begunov
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  4. L. N. Nikitin
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  5. M. I. Buzin
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  6. L. A. Vasserman
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  7. I. S. Chashchin
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  8. A. I. Khlopotinin
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Corresponding author

Correspondence to N. M. Belomoima.

Additional information

Original Russian Text © N.M. Belomoima, E.G. Bulycheva, R.S. Begunov, L.N. Nikitin, M.I. Buzin, L.A. Vasserman, I.S. Chashchin, A.I. Khlopotinin, 2017, published in Doklady Akademii Nauk, 2017, Vol. 475, No. 4, pp. 400–404.

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Belomoima, N.M., Bulycheva, E.G., Begunov, R.S. et al. Dependence of the properties of fluorine-containing poly(phenylquinoxaline) on the method of its preparation. Dokl Chem 475, 159–163 (2017). https://doi.org/10.1134/S001250081708002X

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  • DOI: https://doi.org/10.1134/S001250081708002X

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