Skip to main content
Log in

Selective control of the observables in the ensemble of quantum mechanical molecular systems

  • Topical Issue
  • Published:
Automation and Remote Control Aims and scope Submit manuscript

Abstract

A new approach to synthesize algorithms for selective control of the observables in quantum mechanical systems in the presence of additional constraints during the whole period of control is proposed. Analytic results of achieving the goal of control under some additional assumptions were obtained. It was demonstrated that the error in achieving the goal of control is proportionate to the error in prescribing the initial state of system and the error in realizing the control action. Numerical results for the problem of selective control for energy of hydrogen molecules (H2) with different isotopes are represented. The proposed algorithms are easy to design.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Butkovskii, A.G. and Samoilenko, Yu.I., Upravlenie kvantovomekhanicheskimi protsessami, Moscow: Nauka, 1984. Translated into English under the title Control of Quantum Mechanical Processes and Systems, Dordrecht: Academic, 1990.

    Google Scholar 

  2. Pearson, B.J., White, J.L., Weinacht, T.C., et al., Coherent Control Using Adaptive Learning Algorithms, Phys. Rev. A, 2001, vol. 63, no. 6, pp. 634–676.

    Article  Google Scholar 

  3. Brixner, T., Kiefer, B., and Gerber, G., Problem Complexity in Femtosecond Quantum Control, Chem. Phys., 2001, vol. 267, pp. 241–246.

    Article  Google Scholar 

  4. Rice, S. and Zhao, M., Optical Control of Quantum Dynamics, New York: Wiley, 2000.

    Google Scholar 

  5. Brown, E. and Rabitz, H., Some Mathematical and Algorithmic Challenges in the Control of Quantum Dynamics Phenomena, J. Math. Chem., 2002, vol. 31,no. 1, pp. 17–63.

    Article  MATH  Google Scholar 

  6. Mabuchi, H. and Khaneja, N., Principles and Application of Control in Quantum Systems, Int. J. Robust Nonlinear Control, 2005, no. 15, pp. 646–667.

  7. Bloembergen, N. and Zewail, A.H., Energy Distribution in Isolated Molecules and the Question of Mode-selective Laser Chemistry Revisited, J. Chem. Phys., 1984, vol. 88, pp. 5459–5465.

    Article  Google Scholar 

  8. Goggin, M.E. and Milonni, P.W., Driven Morse Oscillator: Classical Chaos, Quantum Theory and Photodissociation, Phys. Rev. A, 1998, vol. 37, no. 3, pp. 796–806.

    Article  Google Scholar 

  9. Chelkowski, S. and Bandrauk, A.D., Coherent Interaction of an Ultrashort Zero-Area Laser Pulse with a Morse Oscillator, Phys. Rev. A, 1990, vol. 41, pp. 6480–6484.

    Article  Google Scholar 

  10. Goggin, M.E. and Milonni, P.W., Driven Morse Oscillator: Classical Chaos and Quantum Theory for Two-Frequency Dissociation, Phys. Rev. A, 1998, vol. 38, no. 10, pp. 5174–5181.

    Article  Google Scholar 

  11. Liu, W.K., Wu, B., and Yuan, J.M., Nonlinear Dynamics of Chirped Pulse Excitation and Dissociation of Diatomic Molecules, Phys. Rev. Lett., 1995, vol. 75,no. 7, pp. 1292–1295.

    Article  Google Scholar 

  12. Lin, J.T., Lai, T.L., Chuu, D.S., and Jiang, T.F., Quantum Dynamics of a Diatomic Molecule under Chirped Laser Pulses, J. Phys. B, 1998, vol. 31, pp. 117–126.

    Article  Google Scholar 

  13. Anan’evskii, M.S. and Fradkov, A.L., Control of the Observables in the Finite-Level Quantum Systems, Avtom. Telemekh., 2005, no. 5, pp. 63–75.

  14. Ananyevskiy, M.S., Vetchinkin, A.S., Sarkisov, O.M., et al., Quantum Control of Dissociation of an Iodine Molecule by One and Two Femtosecond Laser Pulses Excitation, Proc. Int. Conf. “Physics and Control 2005,” St. Petersburg, 2005, pp. 636–641.

  15. Turinici, G., Ramakhrishna, V., Li, B., and Rabitz, H., Optimal Discrimination of Multiple Quantum Systems: Controllability Analysis, J. Phys. A, 2004, vol. 37, pp. 273–282.

    Article  MATH  Google Scholar 

  16. Miroshnik, I.V., Nikiforov, I.V., and Fradkov, A.L., Nelineinoe i adaptivnoe upravlenie slozhnymi dinamicheskimi sistemami, St. Petersburg: Nauka, 2000. Translated into English under the title Nonlinear and Adaptive Control of Complex Systems, Dordrecht: Academic, 1999.

    Google Scholar 

  17. Peirce, A., Dahleh, M., and Rabitz, H., Optimal Control of Quantum Mechanical Systems: Existence, Numerical Approximations, and Applications, Phys. Rev. A, 1988, vol. 37, pp. 4950–4964.

    Article  Google Scholar 

  18. von Neumann, J.V., Mathematische Grundlagen der Quantenmechanik, Berlin: Springer-Verlag, 1932. Translated under the title Matematicheskie osnovy kvantovoi mekhaniki, Moscow: Nauka, 1964.

    MATH  Google Scholar 

  19. Dirac, P., The Principles of Quantum Mechanics, Oxford: Clarendon, 1930. Translated under the title Printsipy kvantovoi mekhaniki, Moscow: Nauka, 1979.

    MATH  Google Scholar 

  20. Flugge, S., Practical Quantum Mechanics, New York: Springer-Verlag, vol. I, 1974. Translated under the title Zadachi po kvantovoi mekhanike. 1, Moscow: Mir, 1974.

    Google Scholar 

  21. Lions, J.-L., Quelques méthodes de résolution des problèmes aux limites non linéaires, Paris: Dunod et Gauthier-Villars, 1969. Translated under the title Nekotorye metody resheniya nelineinykh kraevykh zadach, Moscow: Mir, 1972.

    MATH  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © M.S. Anan’evskii, 2007, published in Avtomatika i Telemekhanika, 2007, No. 8, pp. 32–43.

This work was supported by the Netherlands Scientific Society and Russian Foundation for Basic Research, joint project no. 047.011.2004.004, Russian Foundation for Basic Research, project no. 00869, and Program 22 of the Presidium of the Russian Academy of Sciences.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Anan’evskii, M.S. Selective control of the observables in the ensemble of quantum mechanical molecular systems. Autom Remote Control 68, 1322–1332 (2007). https://doi.org/10.1134/S0005117907080048

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0005117907080048

PACS numbers

Navigation