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Oxime-Modified Aluminum(III) Isopropoxide: A Promising Sol–Gel Precursor for Corrosion Resistive Nano-Alumina Coating on an Aluminum Alloy

  • Dalip Singh
  • Ajay Saini
  • Veena DhayalEmail author
  • Dinesh Chandra Agarwal
NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
  • 7 Downloads

Abstract

Dense alumina coatings were fabricated over aluminum alloy via dip coating method using oxime-modified aluminum(III) isopropoxide as a sol–gel precursor. The influence of important dip coating parameter; withdrawal rates on quality, thickness, uniformity and corrosion resistivity of coatings were investigated. Structural characterization of coated substrates were done by X-ray diffraction patterns (XRD), scanning electron microscopy (SEM) and atomic force microscopy studies (AFM). Corrosion tests by electrochemical studies indicated that corrosion resistive alumina coatings can be achieved by using withdrawal rate of 25 mm min–1 and 04 cycles of coatings in 3.5% aqueous NaCl solution.

Keywords:

alumina aluminum alloy dip coating corrosion salt spray test 

Notes

ACKNOWLEDGMENTS

Authors are greatful to Material research center, MNIT, Jaipur for AFM analysis, University of Rajasthan for SEM and IIT Roorkee for XRD analysis.

FUNDING

Authors are grateful to ONRG, Singapore for financial support (grant no. N62909-14-1-N042) under NICOP programme.

CONFLICT OF INTEREST

The authors declare that they have no conflict of interest.

REFERENCES

  1. 1.
    Campana, F. and Pilone, D., Scr. Mater., 2009, vol. 60, p. 679.CrossRefGoogle Scholar
  2. 2.
    Wang, J.S., Lee, P.D., Hamilton, R.W., Li, M., and Allison, J., Scr. Mater., 2009, vol. 60, p. 516.CrossRefGoogle Scholar
  3. 3.
    Sha, G., Wang, Y.B., Liao, X.Z., Duan, Z.C., Ringer, S.P., and Langdon, T.G., Acta Mater., 2009, vol. 57, p. 3123.CrossRefGoogle Scholar
  4. 4.
    Senkov, O.N., Shagiev, M.R., Senkova, S.V., and Miracle, D.B., Acta Mater., 2008, vol. 56, p. 3723.CrossRefGoogle Scholar
  5. 5.
    Nie, J.F. and Muddle, B.C., Acta Mater., 2008, vol. 56, p. 3490.CrossRefGoogle Scholar
  6. 6.
    Rooy, E.L., Lampman, S.R., and Zorc, T.B., Properties and Selection: Nonferrous Alloys and Special-Purpose Materials, vol. 2 of ASM Handbook, Metals Park, OH: ASM Int., 1993.Google Scholar
  7. 7.
    Pardo, A., Merino, M.C., Coy, A.E., Arrabal, R., Viejo, F., and Mhich, A., Appl. Surf. Sci., 2007, vol. 253, p. 9164.CrossRefGoogle Scholar
  8. 8.
    Ansari, M.I., Julka, S., Singh, D., and Thakur, G., J. Mol. Liq., 2017, vol. 247, p. 22.CrossRefGoogle Scholar
  9. 9.
    Wang, Z., Wu, L., Qi, Y., Cai, W., and Jiang, Z., Surf. Coat. Technol., 2010, vol. 204, p. 3315.CrossRefGoogle Scholar
  10. 10.
    Lee, C., Int. J. Electrochem. Sci., 2012, vol. 7, p. 12941.Google Scholar
  11. 11.
    Yang, Y., Fu, T., Zhu, J., Fan, J., Zhang, Z., and Zhang, J., Thin Solid Films., 2014, vol. 556, p. 128.CrossRefGoogle Scholar
  12. 12.
    Tarre, A., Aarik, J., Mändar, H., Niilisk, A., Päma, R., Rammula, R., Uustare, T., Rosental, A., and Sammelselg, V., Appl. Surf. Sci., 2008, vol. 254, p. 5149.CrossRefGoogle Scholar
  13. 13.
    Espitia-Cabrera, I., Orozco-Hernandez, H., Torres-Sanchez, R., Contreras Garcia, M.E., Bartolo-Perez, P., and Martinez, L., Mater Lett., 2003, vol. 58, p. 191.CrossRefGoogle Scholar
  14. 14.
    Shen, X., Nie, X., Hu, H., and Tjon, J., Surf. Coat. Technol., 2012, vol. 207, p. 96.CrossRefGoogle Scholar
  15. 15.
    Rodriguez, P., Caussat, B., Iltis, X., Ablitzer, C., and Brothier, M., Chem. Eng. J., 2012, vol. 211, p. 68.CrossRefGoogle Scholar
  16. 16.
    Wu, X., Weng, D., Xu, L., and Li, H., Surf. Coat. Technol., 2001, vol. 145, p. 226.CrossRefGoogle Scholar
  17. 17.
    Watanabe, R., Kawashima, M., and Saito, Y., Thin Solid Films., 2015, vol. 590, p. 98.CrossRefGoogle Scholar
  18. 18.
    Zemanova, M., Fellner, P., and Chovancona, M., Chem. Pap., 1996, vol. 50, p. 55.Google Scholar
  19. 19.
    Kermanpur, A., Ghassemali, E., and Salemizadeh, S., J. Alloys Compd., 2008, vol. 461, p. 331.CrossRefGoogle Scholar
  20. 20.
    Mimura, K. and Kato, K., Jpn. J. Appl. Phys., 2013, vol. 52, pp. 1–5.CrossRefGoogle Scholar
  21. 21.
    Molina, R., Segura, Y., Martínez, F., and Melero, J.A., Chem. Eng. J., 2012, vol. 203, p. 212.CrossRefGoogle Scholar
  22. 22.
    Saini, A., Jat, S.K., Shekhawat, D.S., Kumar, A., Dhayal, V., and Agarwal, D.C., Mater. Res. Bull., 2017, vol. 93, p. 373.CrossRefGoogle Scholar
  23. 23.
    Bradley, D.C., Mehrotra, R.C., Rothwell, I.P., and Singh, A., Alkoxo and Aryloxo Derivatives of Metal, London: Academic Press, 2001.Google Scholar
  24. 24.
    Vogel, A.I., Textbook of Quantitative Chemical Analysis, London: Longmans, 1989.Google Scholar
  25. 25.
    Oesper, R.E. and Kjeldahl, J., J. Chem. Educ., 1934, vol. 11, p. 457.CrossRefGoogle Scholar
  26. 26.
    Bradley, D.C., Halim, A.E., and Wardlaw, W., J. Chem. Soc., 1950, p. 3450.Google Scholar
  27. 27.
    Valdez, B., Kiyota, S., Stoytcheva, M., Zlatev, R., and Bastidas, J.M., Corros. Sci., 2014, vol. 87, p. 141.CrossRefGoogle Scholar
  28. 28.
    Golrua, S.S., Attara, M.M., and Ramezanzadeh, B., Prog. Org. Coat., 2014, vol. 77, p. 1391.CrossRefGoogle Scholar
  29. 29.
    Rahimi, H., Mozaffarinia, R., and Najafabadi, A.H., J. Mater. Sci. Technol., 2013, vol. 29, p. 603.CrossRefGoogle Scholar
  30. 30.
    Hamid, M.A. and Rahman, I.A., Malays. J. Chem., 2003, vol. 5, p. 86.Google Scholar
  31. 31.
    Jungsuwattanon, K., Saesoo, S., Pimpha, N., and Negishi, N., CMU J. Nat. Sci. Spec. Issue Nanotechnol., 2008, vol. 7, p. 25.Google Scholar
  32. 32.
    Rahimi, H., Mozaffarinia, R., Najafabadi, A.H., Razavi, R.S., and Paimozd, E., Prog. Org. Coat., 2013, vol. 76, p. 307.CrossRefGoogle Scholar
  33. 33.
    Bardi, U., Caporali, S., Craig, M., Giorgetti, A., Perissi, I., and Nicholls, J.R., Surf. Coat. Technol., 2009, vol. 203, p. 1373.CrossRefGoogle Scholar
  34. 34.
    Onofre-Bustamante, E., Dominguez-Crespo, M.A., Torres-Huerta, A.M., Olvera- Martinez, A., and Genesca-Llongueras, J., J. Solid State Electrochem., 2009, vol. 13, p. 1785.CrossRefGoogle Scholar
  35. 35.
    Stefanov, P., Atanasova, G., Stoychev, D., and Marinova, T.S., Surf. Coat. Technol., 2004, vol. 180, p. 446.CrossRefGoogle Scholar
  36. 36.
    Shan, C.X., Hou, X., and Choy, K.L., Surf. Coat. Technol., 2008, vol. 202, p. 2399.CrossRefGoogle Scholar
  37. 37.
    Deyab, M.A., Riccardis, A. D., and Mele, G., J. Mol. Liq., 2016, vol. 220, p. 517.CrossRefGoogle Scholar
  38. 38.
    Zheng, X., Zhang, S., Li, W., Gong, M., and Yin, L., Corros. Sci., 2015, vol. 95, p. 168.CrossRefGoogle Scholar
  39. 39.
    Capelossi, V.R., Poelman, M., Recloux, I., Hernandez, R.P., and Demelo, H.G., Electrochim. Acta, 2014, vol. 124, p. 69.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Dalip Singh
    • 1
  • Ajay Saini
    • 2
  • Veena Dhayal
    • 2
    Email author
  • Dinesh Chandra Agarwal
    • 3
  1. 1.School of Automobile Mechanical and Mechatronics, Manipal University JaipurJaipurIndia
  2. 2.Department of Chemistry, Manipal University JaipurJaipurIndia
  3. 3.National Institute for Research and Development in Defence Shipbuilding (NIRDESH)New DelhiIndia

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