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Processes of Altax Production

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Abstract

Works on existing ways of producing Altax (2,2'-dibenzothiazolyl disulfide), an important accelerator of rubber vulcanization, are analyzed. It is shown that the main means of its production is the oxidation of 2-mercaptobenzothiazole (Captax) by different oxidizers (e.g., oxygen in the presence of catalysts, hydrogen peroxide) and electrochemical oxidation. Based on the analysis of the literature data, a small-scale Altax production technology is developed at the Boreskov Institute of Catalysis and tested at a pilot plant designed at the institute’s Volgograd Branch.

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REFERENCES

  1. 1

    Gromova, A. and Tsekhonya, V., Khim. Zh., 2004, no. 9, pp. 18–23.

  2. 2

    European Rubber Journal. https://www.european-rubber-journal.com/. Cited October 4, 2019.

  3. 3

    Kirk-Othmer Encyclopedia of Chemical Technology, 5th ed., New York: Wiley, 2006, vol. 21, p. 219.

  4. 4

    Kandyrin, K. and Frolikova, V., Khim. Biznes, 2007, no. 5, pp. 44–49.

  5. 5

    Ahsan, O., Mohamad, N., and Soh, T.C Int. J. Automot. Mech. Eng., 2015, vol. 12, pp. 2954–2966.

  6. 6

    Ohnuki, T., Nippon Gomu Kyokaishi, 2014, vol. 87, no. 12, pp. 467–472.

  7. 7

    USSR Inventor’s Certificate no. 3 939 603, 1985.

  8. 8

    RF Patent 2492055, 2013.

  9. 9

    USSR Inventor’s Certificate no. 1 281 573, 1987.

  10. 10

    Chemical Industry. Chemicals Description, Manufacturers Directory. http://chemindustry.ru. Cited October 4, 2019.

  11. 11

    JSC Volzhsky Orgsynthese. Official Website. https:// www.zos-v.ru/en/. Cited October 4, 2019.

  12. 12

    Klepikov, D.N., Vygolov, N.V., and Il’inykh, L.V., Vestn. Khim. Prom-sti, 2006, no. 5, pp. 18–22.

  13. 13

    Comprehensive Heterocyclic Chemistry, Katritzky, A.R. and Rees, C.W., Eds., Oxford: Pergamon Press, 1984, vol. 6.

  14. 14

    Oae, S., Khimiya organicheskikh soedinenii sery (Chemistry of Organic Sulfur Compounds), Moscow: Khimiya, 1975.

  15. 15

    Gogin, L.L., Zhizhina, E.G., Pai, Z.P., and Parmon, V.N., Chem. Sustainable Dev., 2012, no. 3, pp. 227–235.

  16. 16

    Khimicheskaya entsiklopediya (Chemical Encyclopedia), Moscow: Bol’shaya Rossiiskaya Entsiklopediya, 1995, vol. 4.

  17. 17

    Koval’, I.V., Russ. Chem. Rev., 1993, vol. 62, no. 8, pp. 769–786.

  18. 18

    Gantman, M.G., Catalysis of radical processes with copper complexes: role of organic ligands, Cand. Sci. (Chem.), Moscow: Moscow State Univ., 2008.

  19. 19

    Sharipov, A.Kh., Katal. Prom-sti, 2008, no. 4, pp. 18–26.

  20. 20

    US Patent 2 024 567, 1933.

  21. 21

    USSR Inventor’s Certificate, 1991.

  22. 22

    USSR Inventor’s Certificate no. 915802, 1982.

  23. 23

    EP Patent 0 112 794, 1982.

  24. 24

    US Patent 5 659 086, 1997.

  25. 25

    US Patent 6 610 857, 2003.

  26. 26

    US Patent 4 143 045, 1979.

  27. 27

    ChSSR Inventor’s Certificate no. 254947, 1988.

  28. 28

    DE Patent 2 355 897, 1974.

  29. 29

    US Patent 4 307 236, 1981.

  30. 30

    USSR Inventor’s Certificate no. 420247, 1976.

  31. 31

    Kovalenko, I.P., Sarkisyan, L.G., and Savilova, V.G., Abstracts of Papers, Trudy IX Vsesoyuznoi nauchno-tekhnicheskoi conferentsii (Proc. IX All-Union Sci.-Techn. Conf.), Tambov, 1990, pp. 91–92.

  32. 32

    US Patent 6 124 467, 2000.

  33. 33

    Blokh, G.A., Organicheskie uskoriteli vulkanizatsii i vulkaniziruyushchie sistemy dlya elastomerov (Organic Boosters and Vulcanizing Systems for Elastomers), Leningrad: Khimiya, 1978.

  34. 34

    RF Patent 2 019 544, 1994.

  35. 35

    US Patent 2 267 347, 1941.

  36. 36

    EP Patent 0 135 102, 1985.

  37. 37

    US Patent 4 482 720, 1984.

  38. 38

    Kilimnik, A.B. and Bakunin, E.S., Vestn. Tambov. Gos. Tekh. Univ., 2011, vol. 17, no. 4, pp. 1007–1021.

  39. 39

    US Patent 4 591 647, 1986.

  40. 40

    USSR Inventor’s Certificate no. 1627085, 1991.

  41. 41

    GB Patent 915 932, 1961.

  42. 42

    Boyarshinov, A.B., Abstract of Papers, Trudy XIII Sovbeshchaniya po elektrokhimii organicheskikh soedinenii (Proc. XIII Conf. on Electrochemistry of Organic Compounds), Tambov, 1994, pp. 159–160.

  43. 43

    Rapoport, Yu.M., Khim. Prom-st', 1996, no. 4, pp. 19–21.

  44. 44

    RF Patent 2 479 581, 2013.

  45. 45

    Bakunin, E.S., Kilimnik, A.B., and Ivliev, A.A., Vestn. Tambov. Gos. Tekh. Univ., 2012, vol. 18, no. 3, pp. 644–648.

  46. 46

    Pai, Z.P. and Parmon, V.N., Abstract of Papers, Trudy XXVII Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Khimicheskie reaktivy, reagenty i protsessy malotonnazhnoi khimii "Reaktiv-2013”” (Proc. XXVII Int. Sci.-Techn. Conf. "Chemicals, Reagents, and Processes of Low-Capacity Chemistry “Reaktiv-2013””), Irkutsk, 2013, p. 13.

  47. 47

    Pai, Z.P., Abstract of Papers, Trudy II Rossiiskogo kongressa po katalizu “Roskataliz” (Proc. II Russ. Congress on Catalysis “Roskataliz”), Samara, 2014, vol. 1, p. 232.

  48. 48

    Pai, Z.P. and Parmon, V.N., Abstract of Papers, Trudy XXIX Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Khimicheskie reaktivy, reagenty i protsessy malotonnazhnoi khimii “Reaktiv-2015””, (Proc. XXIX Int. Sci.-Techn. Conf. "Chemicals, Reagents, and Processes of Low-Capacity Chemistry “Reaktiv-2015””), Novosibirsk, 2015, p. 25.

  49. 49

    Pai, Z.P. and Parmon, V.N., Abstract of Papers, Trudy XXX Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Khimicheskie reaktivy, reagenty i protsessy malotonnazhnoi khimii “Reaktiv-2016”” (Proc. XXX Int. Sci.-Techn. Conf. “Chemicals, Reagents, and Processes of Low-Capacity Chemistry “Reaktiv-2016””), Ufa, 2016, p. 48.

  50. 50

    Pai, Z.P. and Parmon, V.N., Abstract of Papers, Trudy III Rossiiskogo kongressa po katalizu “Roskataliz” (Proc. III Russ. Congress on Catalysis), Novgorod, 2017, p. 30.

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Correspondence to L. L. Gogin or E. G. Zhizhina or Z. P. Pai.

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Translated by V. Glyanchenko

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Gogin, L.L., Zhizhina, E.G. & Pai, Z.P. Processes of Altax Production. Catal. Ind. 11, 271–277 (2019). https://doi.org/10.1134/S2070050419040056

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Keywords:

  • vulcanization accelerator
  • Altax
  • Captax
  • oxidation