Catalysis in Industry

, Volume 10, Issue 2, pp 118–125 | Cite as

Hydroisomerization of Benzene-Containing Gasoline Fraction on Pt/B2O3–Al2O3 and Pt/WO3–Al2O3 Catalysts

  • E. A. BuluchevskiiEmail author
  • E. D. Fedorova
  • A. V. Lavrenov
  • M. V. Zhuravleva
Catalysis in Petroleum Refining Industry


The effect of the hydroisomerization conditions of the benzene-containing fraction of catalytic reforming gasoline on the yield and composition of products is studied on Pt/B2O3–Al2O3 and Pt/WO3–Al2O3 catalysts. These catalysts allow benzene to be completely removed from the raw material. At the same time, the greatest yields of liquid products are obtained with minimal losses of the octane number at 2 MPa, a mass feedstock hourly space velocity (MFHSV) of 2 h−1, and 325°C: 96.3 and 95.4 wt % on Pt/B2O3–Al2O3 and Pt/WO3–Al2O3 catalysts, respectively. The activity of the catalysts is maintained for 100 h during their operation.


benzene removal hydroisomerization benzene-containing fraction Euro-5 gasoline 


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  1. 1.
    TR TS (Customs Union Technical Regulation) 013/2011: Requirements to Automobile and Aviation Gasoline, Diesel and Ship Fuel, Jet Engine Fuel and Furnace Boiler Oil, 2011.Google Scholar
  2. 2.
    Levinbuk, M.I., Netesanov, S.D., Lebedev, A.A., Borodacheva, A.V., and Sizova, E.V., Pet. Chem., 2007, vol. 47, no. 4, pp. 230–244.CrossRefGoogle Scholar
  3. 3.
    Belyi, A.S., Katal. Prom-sti, 2014, no. 5, pp. 23–28.Google Scholar
  4. 4.
    Keenan, J.J., Gaffney, S.H., Galbraith, D.A., Beatty, P., and Paustenbach, D.J., Chem.-Biol. Interact., 2010, vol. 184, nos. 1–2, pp. 293–295.CrossRefPubMedGoogle Scholar
  5. 5.
    Mirimanyan, A.A., Vikhman, A.G., Mkrtychev, A.A., Maryshev, V.B., Borutskii, P.N., and Mozhaiko, V.N., Neftepererab. Neftekhim., 2006, no. 8, pp. 11–14.Google Scholar
  6. 6.
    Laredo, G.C., Marroquin, J.O., Castillo, J., Perez-Romo, P., and Navarrete-Bolaños, J., Appl. Catal., A, 2009, vol. 363, nos. 1–2, pp. 19–26.CrossRefGoogle Scholar
  7. 7.
    Akhmetov, T.V. and Abdul’minev, K.G., Neftepererab. Neftekhim., 2009, no. 1, pp. 12–15.Google Scholar
  8. 8.
    Carrero-Mantilla, J. and Llano-Restrepo, M., Fluid Phase Equilib., 2004, vol. 219, no. 2, pp. 181–193.CrossRefGoogle Scholar
  9. 9.
    Zhorov, Yu.M., Termodinamika khimicheskikh protsessov (Thermodynamics of Chemical Processes), Moscow: Khimiya, 1985.Google Scholar
  10. 10.
    US Patent 5830345, 1998.Google Scholar
  11. 11.
    RF Patent 2287369, 2006.Google Scholar
  12. 12.
    Gopal, S. and Smirniotis, P.G., Appl. Catal., A, 2003, vol. 247, no. 1, pp. 113–123.CrossRefGoogle Scholar
  13. 13.
    Tanatarov, M.A., Akhmetov, A.F., Shipikin, V.V., and Georgievskii, V.Yu., Proizvodstvo neetilirovannykh benzinov: Tematicheskii obzor (Production of Unleaded Gasolines: Subject Review), Moscow: TsNIITEneftekhim, 1981.Google Scholar
  14. 14.
    Shimizu, K., Sunagawa, T., Vera, C.R., and Ukegawa, K., Appl. Catal., A, 2001, vol. 206, no. 1, pp. 79–86.CrossRefGoogle Scholar
  15. 15.
    Kazakov, M.O, Lavrenov, A.V., and Duplyakin, V.K., Catal. Ind., 2013, vol. 5, no. 3, pp. 209–215.CrossRefGoogle Scholar
  16. 16.
    Busto, M., Grau, J.M., Canavese, S., and Vera, C.R., Energy Fuels, 2009, vol. 23, no. 2, pp. 599–606.CrossRefGoogle Scholar
  17. 17.
    Miyaji, A. and Okuhara, T., Catal. Today, 2003, vol. 81, no. 1, pp. 43–49.CrossRefGoogle Scholar
  18. 18.
    Fedorova, E.D., Kazakov, M.O., Lavrenov, A.V., Buyalskaya, K.S., Leontyeva, N.N., Gulyaeva, T.I., and Shilova, A.V., Chem. Sustainable Dev., 2013, vol. 21, no. 1, pp. 107–113.Google Scholar
  19. 19.
    Fedorova, E.D., Buluchevskii, E.A., Lavrenov, A.V., Leont’eva, N.N., Gulyaeva, T.I., and Shilova, A.V., Khim. Interes. Ust. Razv., 2014, vol. 22, no. 6, pp. 553–559.Google Scholar
  20. 20.
    Smyshlyaeva, Yu.A., Ivanchina, E.D., Kravtsov, A.V., Zuong, C.H.T., and Fan, F. Izv. Tomsk. Politech. Univ., Ser. Khim., 2011, vol. 318, no. 3, pp. 75–80.Google Scholar
  21. 21.
    Bragin, O.V. and Liberman. A., Prevrashchenie uglevodorodov na metallsoderzhashchikh katalizatorakh (Conversion of Hydrocarbons on Metal-Containing Catalysts), Moscow: Khimiya, 1981.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. A. Buluchevskii
    • 1
    • 2
    Email author
  • E. D. Fedorova
    • 1
  • A. V. Lavrenov
    • 1
  • M. V. Zhuravleva
    • 1
  1. 1.Institute of Problems of Hydrocarbon Processing, Siberian BranchRussian Academy of SciencesOmskRussia
  2. 2.Omsk State UniversityOmskRussia

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