The effect of the relative content of single-walled carbon nanotubes (SWCNTs) on the compaction, phase composition, microstructure, and mechanical properties of composites based on yttria-stabilized zirconia obtained via spark plasma sintering is studied. We found that a substantial increase in the relative density from 98.26 to 99.98% is observed in the composites containing 0.1 and 0.5 wt % SWCNT. It is established that SWCNTs partially limit the monoclinic–tetragonal transition occurring during high-temperature treatment of zirconia. The fracture toughness of the composite containing 1 wt % SWCNT increases by 38% compared to ceramics without additives.
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T. V. Hughes and C. R. Chambers, “Manufacture of carbon filaments,” US Patent No. 405480 (1889).
P. Schutzenberger and L. Schutzenberger, “Sur quelques faits relatifs l’histoire du carbone,” Acad. Sci. Paris 111, 774 (1890).
L. V. Radushkevich and V. M. Luk’yanovich, “On the structure of carbon formed during the thermal decomposition of carbon monoxide on an iron contact,” Zh. Fiz. Khim. 26, 88 (1952).
S. Iijima, “Helical microtubules of graphitic carbon,” Nature (London, U.K.) 354, 56 (1991). https://doi.org/10.1038/354056a0
S. S. Samal and S. Bal, “Carbon nanotube reinforced ceramic matrix composite—a review,” J. Min. Mater. Char. Eng. 7, 4236 (2008). https://doi.org/10.4236/jmmce.2008.74028
A. Peigney, C. H. Laurent, E. Flahaut, and A. Rousset, “Carbon nanotubes in novel ceramic matrix nanocomposites,” Ceram. Int. 26, 677 (2000). https://doi.org/10.1016/S0272-8842(00)00004-3
M. Yu, O. Lourie, M. J. Dyer, et al., “Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load,” Science (Washington, DC, U. S.) 287, 1126 (2000). https://doi.org/10.1126/science.287.5453.637
M. Yu, B. S. Files, S. Arepalli, and R. S. Ruoff, “Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties,” Phys. Rev. Lett. 84, 5552 (2000). https://doi.org/10.1103/PhysRevLett.84.5552
A. Thess, R. Lee, P. Nikolaev, et al., “Crystalline ropes of metallic carbon nanotubes,” Science (Washington, DC, U. S.) 273, 483 (1996). https://doi.org/10.1126/science.273.5274.483
Y. Ando, X. Zhao, H. Shimoyama, et al., “Physical properties of multiwalled carbon nanotubes,” Int. J. Inorg. Mater. 1, 77 (1999). https://doi.org/10.1016/S1463-0176(99)00012-5
S. Berber, Y. K. Kwon, and D. Tomanek, “Unusually high thermal conductivity of carbon nanotubes,” Phys. Rev. Lett. 84, 4613 (2000). https://doi.org/10.1103/PhysRevLett.84.4613
P. Kim, L. Shi, A. Majumdar, and P. L. McEuen, “Thermal transport measurements of individual multiwalled nanotubes,” Phys. Rev. Lett. 87, 215502 (2001). https://doi.org/10.1103/PhysRevLett.87.215502
E. A. Lyapunova, M. V. Grigor’ev, A. P. Skachkov, et al., “Structure and mechanical properties of zirconium oxide modified with carbon nanotubes,” Vestn. PNIPU, Mekh., No. 4, 10 (2015).https://doi.org/10.15593/perm.mech/2015.4.18
Yu. I. Golovin, B. Ya. Farber, V. V. Korenkov, et al., “Mechanical properties of baddeleyite nanoceramics modified by carbon nanotubes,” Vestn. TGU, Estestv. Tekh. Nauki 17, 1380 (2012).
A. A. Leonov, “Microstructure and properties of single wall carbon nanotubes/zirconia composite,” in Proceedings of the International Conference with School and Master-Classes for Young Scientists on Chemical Technology of Functional Materials, Moscow, Nov. 30–Dec. 1,2017 (RKhTU im. D.I. Mendeleeva, Moscow, 2017), p. 35.
Yu. I. Golovin, A. I. Tyurin, V. V. Korenkov, V. V. Rodaev, A. O. Zhigachev, A. V. Umrikhin, T. S. Pirozhkova, and S. S. Razlivalova, “Effect of carbon nanotubes on strength characteristics of nanostructured ceramic composites for biomedicine,” Nanotechnol. Russ. 13, 168 (2018).
J. H. Shin and S. H. Hong, “Microstructure and mechanical properties of single wall carbon nanotube reinforced yttria stabilized zircona ceramics,” Mater. Sci. Eng., A 556, 382 (2012). https://doi.org/10.1016/j.msea.2012.07.001
J. P. Zhou, Q. M. Gong, K. Y. Yuan, et al., “The effects of multiwalled carbon nanotubes on the hot-pressed 3 mol % yttria stabilized zirconia ceramics,” Mater. Sci. Eng. A 520, 153 (2009). https://doi.org/10.1016/j.msea.2009.05.014
A. Leonov, “Effect of alumina nanofibers content on the microstructure and properties of ATZ composites fabricated by spark plasma sintering,” Mater. Today: Proc. 11, 66 (2019). https://doi.org/10.1016/j.matpr.2018.12.108
A. A. Leonov and E. V. Abdulmenova, “Alumina-based composites reinforced with single-walled carbon nanotubes,” IOP Conf. Ser.: Mater. Sci. Eng. 511, 012001 (2019). https://doi.org/10.1088/1757-899X/511/1/012001
G. R. Anstis, P. Chantikul, B. N. Lawn, and D. B. Marshall, “A critical evaluation of indentation techniques for measuring fracture toughness: I, direct crack measurements,” J. Am. Ceram. Soc. 64, 533 (1981). https://doi.org/10.1111/j.1151-2916.1981.tb10320.x
A. Kasperski, A. Weibel, D. Alkattan, et al., “Microhardness and friction coefficient of multi-walled carbon nanotube-yttria-stabilized ZrO2 composites prepared by spark plasma sintering,” Scr. Mater. 69, 338 (2013). https://doi.org/10.1016/j.scriptamat.2013.05.015
R. Hassan, A. Nisar, S. Ariharan, et al., “Multi-functionality of carbon nanotubes reinforced 3 mol % yttria stabilized zirconia structural biocomposites,” Mater. Sci. Eng., A 704, 329 (2017). https://doi.org/10.1016/j.msea.2017.08.039
M. Mazaheri, D. Mari, Z. R. Hesabi, et al., “Multi-walled carbon nanotube/nanostructured zirconia composites: outstanding mechanical properties in a wide range of temperature,” Compos. Sci. Technol. 71, 939 (2011). https://doi.org/10.1016/j.compscitech.2011.01.017
L. Shen, Y. H. Han, C. Xiang, et al., “Phase transformation behavior of ZrO2 by addition of carbon nanotubes consolidated by spark plasma sintering,” Scr. Mater. 69, 736 (2013). https://doi.org/10.1016/j.scriptamat.2013.08.015
L. Melk, J. J. Roa Rovira, F. Garcaía-Marro, et al., “Nanoindentation and fracture toughness of nanostructured zirconia/multi-walled carbon nanotube composites,” Ceram. Int. 41, 2453 (2015). https://doi.org/10.1016/j.ceramint.2014.10.060
R. Poyato, J. Macias-Delgado, A. Gallardo-López, et al., “Microstructure and impedance spectroscopy of 3YTZP/SWNT ceramic nanocomposites,” Ceram. Int. 41, 12861 (2015). https://doi.org/10.1016/j.ceramint.2015.06.123
R. Poyato, A. Gallardo-López, F. Gutiérrez-Mora, et al., “Effect of high SWNT content on the room temperature mechanical properties of fully dense 3YTZP/SWNT composites,” J. Eur. Ceram. Soc. 34, 1571 (2014). https://doi.org/10.1016/j.jeurceramsoc.2013.12.024
M. H. Bocanegra-Bernal, A. Reyes-Rojas, A. Aguilar-Elguezabal, et al., “X-ray diffraction evidence of a phase transformation in zirconia by the presence of graphite and carbon nanotubes in zirconia toughened alumina composites,” Int. J. Refract. Met. Hard Mater. 35, 315 (2012). https://doi.org/10.1016/j.ijrmhm.2012.07.004
A. A. Leonov, A. O. Khasanov, V. A. Danchenko, and O. L. Khasanov, “Spark plasma sintering of ceramic matrix composite based on alumina, reinforced by carbon nanotubes,” IOP Conf. Ser.: Mater. Sci. Eng. 286, 012034 (2017). https://doi.org/10.1088/1757-899X/286/1/012034
G. Yamamoto, Y. Sato, T. Takahashi, et al., “Preparation of single-walled carbon nanotube solids and their mechanical properties,” J. Mater. Res. 20, 2609 (2005). https://doi.org/10.1557/JMR.2005.0345
A. Datye, K. Wu, G. Gomes, et al., “Synthesis, microstructure and mechanical properties of yttria stabilized zirconia (3YTZP)-multi-walled nanotube (MWNTs) nanocomposite by direct in-situ growth of MWNTs on zirconia particles,” Compos. Sci. Technol. 70, 2086 (2010). https://doi.org/10.1016/j.compscitech.2010.08.005
R. Poyato, J. Macias-Delgado, A. Garcia-Valenzuela, et al., “Mechanical and electrical properties of low SWNT content 3YTZP composites,” J. Eur. Ceram. Soc. 35, 2351 (2015). https://doi.org/10.1016/j.jeurceramsoc.2015.02.022
A. Kasperski, A. Weibel, D. Alkattan, et al., “Double-walled carbon nanotube/zirconia composites: preparation by spark plasma sintering, electrical conductivity and mechanical properties,” Ceram. Int. 41, 13731 (2015). https://doi.org/10.1016/j.ceramint.2015.08.034
G. Suárez, B. K. Jang, E. F. Aglietti, and Y. Sakka, “Fabrication of dense ZrO2/CNT composites: influence of bead-milling treatment,” Metall. Mater. Trans. A 44, 4374 (2013). https://doi.org/10.1007/s11661-013-1775-y
The authors are grateful to M.R. Predtechenskii and A.E. Bezrodnyi for providing “Tuball” single-walled carbon nanotubes.
The study was performed on the basis of Nano Center of National Research Tomsk Polytechnic University.
Translated by O. Kadkin
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Leonov, A.A., Dvilis, E.S., Khasanov, O.L. et al. CERAMIC COMPOSITE BASED ON ZIRCONIA REINFORCED BY SINGLE-WALLED CARBON NANOTUBES. Nanotechnol Russia 14, 118–124 (2019) doi:10.1134/S1995078019020095