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Russian Journal of Physical Chemistry B

, Volume 13, Issue 5, pp 789–802 | Cite as

New Cocatalyst for Alkene Polymerization Reactions with Transition Metal Catalysts

  • L. A. RishinaEmail author
  • Y. V. Kissin
  • S. Ch. Gagieva
  • S. S. Lalayan
CHEMICAL PHYSICS OF POLYMER MATERIALS
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Abstract

The effect of a cocatalyst in alkene homo- and copolymerizations with transition metal catalysts of different types was studied. The results of studies of polymerizations of ethylene, propylene, and higher linear 1-alkenes and copolymerizations of ethylene with linear 1-alkenes using catalysts of different types in combination with a binary cocatalyst Al(C2H5)2Cl/Mg(C4H9)2 at [Al] : [Mg] > 2.5 were summarized. The traditional Ziegler–Natta catalysts (TiCl4, Ti(Oi-C3H7)4, and TiCl3 ) and titanium postmetallocene complexes with various organic ligands were studied. The binary cocatalyst significantly increased the activity of the traditional catalysts compared with that of Al(C2H5)2Cl and the activity of postmetallocene complexes compared with that of polymethylaluminoxane (MAO). The active centers of these catalytic systems differ in their kinetic parameters, stereospecificity, and copolymerization ability. The efficiency of the Al(C3H5)2Cl/Mg(C4H9)2 cocatalyst can be explained by the in situ formation of finely dispersed MgCl2 and immobilization of the cationic active centers on its surface.

Keywords:

alkene polymerization transition metal catalysts kinetics molecular mass distribution gel permeation chromatography IR and NMR spectroscopy differential scanning calorimetry X-ray diffraction analysis 
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Notes

FUNDING

This study was performed under state assignment and supported by the Russian Scientific Foundation (project no. 18-13-00375).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • L. A. Rishina
    • 1
    Email author
  • Y. V. Kissin
    • 2
  • S. Ch. Gagieva
    • 3
  • S. S. Lalayan
    • 1
  1. 1.Semenov Institute of Chemical Physics, Russian Academy of SciencesMoscowRussia
  2. 2.Rutgers, The State University of New Jersey, Department of Chemistry and Chemical BiologyNJUSA
  3. 3.Moscow State UniversityMoscowRussia

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