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Russian Journal of Physical Chemistry B

, Volume 13, Issue 3, pp 554–556 | Cite as

Initiator Based on the Cu(II) and Cetyl Trimethyl Ammonium Bromide Compounds that Generates Free Radicals in the Decomposition of tert-Butyl Hydroperoxide in Optimum Temperature Conditions

  • L. A. SmurovaEmail author
  • Z. S. Kartasheva
SHORT COMMUNICATIONS

Abstract

The two-component composition consisting of complex copper Cu(II) compounds and cationic surface-activated substance cetyl trimethyl ammonium bromide (CTAB) exhibits high catalytic reactivity during decomposition of tert-butyl hydroperoxide. One specific characteristic of the effects of the Cu(II) + CTAB binary system consists in its high rate of processing without visible signs of deactivation in the transformation of significant amounts of the reagent in optimum temperature conditions.

Keywords:

complex Cu(II) compounds cetyl trimethyl ammonium bromide tert-butyl hydroperoxide 

Notes

FUNDING

This study was carried out under the government contract of Federal Agency for Scientific Organizations of Russia (0082-2018-0006, no. AAAA-A18-118020890097-1).

REFERENCES

  1. 1.
    L. M. Pisarenko, T. V. Maksimova, and O. T. Kasaikina, Russ. Chem. Bull. 54, 1855 (2005).CrossRefGoogle Scholar
  2. 2.
    O. T. Kasaikina, N. V. Potapova, D. A. Krugovov, and L. M. Pisarenko, Kinet. Catal. 58, 556 (2017).CrossRefGoogle Scholar
  3. 3.
    A. B. Gagarina, L. A. Smurova, E. N. Degtyarev, and A. G. Kozyreva, Russ. J. Phys. Chem. B 3, 877 (2009).CrossRefGoogle Scholar
  4. 4.
    N. A. Turovskij, Yu. V. Berestneva, E. V. Raksha, I. A. Opeida, and M. Yu. Zubritskii, Russ. Chem. Bull. 63, 1717 (2014).CrossRefGoogle Scholar
  5. 5.
    N. A. Turovskij, E. V. Raksha, and O. I. Gevus, Oxidation Commun. 32, 69 (2009).Google Scholar
  6. 6.
    L. A. Smurova, A. B. Gagarina, and N. M. Emmanuel’, Dokl. Akad. Nauk SSSR 272, 141 (1983).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Semenov Institute of Chemical Physics of Russian Academy of SciencesMoscowRussia

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