Initiator Based on the Cu(II) and Cetyl Trimethyl Ammonium Bromide Compounds that Generates Free Radicals in the Decomposition of tert-Butyl Hydroperoxide in Optimum Temperature Conditions
The two-component composition consisting of complex copper Cu(II) compounds and cationic surface-activated substance cetyl trimethyl ammonium bromide (CTAB) exhibits high catalytic reactivity during decomposition of tert-butyl hydroperoxide. One specific characteristic of the effects of the Cu(II) + CTAB binary system consists in its high rate of processing without visible signs of deactivation in the transformation of significant amounts of the reagent in optimum temperature conditions.
Keywords:complex Cu(II) compounds cetyl trimethyl ammonium bromide tert-butyl hydroperoxide
This study was carried out under the government contract of Federal Agency for Scientific Organizations of Russia (0082-2018-0006, no. AAAA-A18-118020890097-1).