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Russian Journal of Physical Chemistry B

, Volume 13, Issue 3, pp 514–518 | Cite as

Kinetics of the Thermal Destruction of Polyvinyl Alcohol in Composites with Boron Polyoxide. Part 2. Analysis of the Products of Thermal Destruction

  • E. V. KoverzanovaEmail author
  • S. V. Usachev
  • S. M. Lomakin
  • N. G. Shilkina
  • A. Yu. Shaulov
  • Al. Al. Berlin
CHEMICAL PHYSICS OF POLYMER MATERIALS

Abstract

The effect of boric acid (BA) on the thermal destruction of polyvinyl alcohol (PVA) was studied. The pyrolysis temperatures were chosen based on the thermogravimetric analysis data. The composition of the main products of pyrolysis was determined. The mechanisms of thermal destruction were proposed for PVA and its composite with BA. The observed phenomena associated with the effect of the filler on the composition of the products of PVA pyrolysis were explained.

Keywords:

thermal destruction pyrolysis boron polyoxide gas chromato-mass spectrometry polyvinyl alcohol 

Notes

FUNDING

This study was performed under state assignment of the Federal Agency for Scientific Organizations of Russia (topic nos. 0082-2014-0009 АААА-А17-117040610309-0, 0082-2014-0011 АААА-А17-117111600093-8, and 0120125305).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • E. V. Koverzanova
    • 1
    Email author
  • S. V. Usachev
    • 1
  • S. M. Lomakin
    • 2
  • N. G. Shilkina
    • 1
  • A. Yu. Shaulov
    • 1
  • Al. Al. Berlin
    • 1
  1. 1.Semenov Institute of Chemical Physics, Russian Academy of SciencesMoscowRussia
  2. 2.Emanuel Institute of Biochemical Physics, Russian Academy of SciencesMoscowRussia

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