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Polymer Science, Series C

, Volume 61, Issue 1, pp 49–57 | Cite as

Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

  • A. A. Lyapkov
  • G. S. Bozhenkova
  • N. A. Smirnova
  • N. I. Prokudina
  • M. S. Yusubov
  • F. VerpoortEmail author
Article
  • 10 Downloads

Abstract

In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

Notes

FUNDING

The authors acknowledge the support from the Russian Foundation for Basic Research (no. 18-29-04047) and Tomsk Polytechnic University Competitiveness Enhancement Program grant (VIU-195/2018).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. A. Lyapkov
    • 1
  • G. S. Bozhenkova
    • 2
  • N. A. Smirnova
    • 1
  • N. I. Prokudina
    • 1
  • M. S. Yusubov
    • 1
  • F. Verpoort
    • 1
    • 3
    Email author
  1. 1.National Research Tomsk Polytechnic UniversityTomskRussia
  2. 2.Tomsk Oil and Gas Research and Design InstituteTomskRussia
  3. 3.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of TechnologyWuhanChina

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