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Polymer Science, Series C

, Volume 61, Issue 1, pp 102–106 | Cite as

Stereoselective synthesis and metathesis polymerization of exo-5-(Pentamethyldisiloxanyl) norbornene

  • M. A. Guseva
  • D. A. Alentiev
  • D. I. Gavrilov
  • E. V. Bermesheva
  • P. P. Chapala
  • E. Sh. Finkelshtein
  • M. V. BermeshevEmail author
Article
  • 17 Downloads

Abstract

A one-step selective method based on the hydrosilylation of 2,5-norbornadiene with commercially available silanes in the presence of a Pd-catalyst and bulky ligand R-MOP is developed for the synthesis of exo-isomers of silicon-containing norbornenes. This approach leads to the formation of exclusively exo-isomers. The absence of the steps of alkylation with organometallic reagents and photochemical isomerization makes the proposed approach attractive for the targeted design and synthesis of new polymeric materials with the required properties.

Notes

FUNDING

The study was supported by the Russian Science Foundation (project 18-13-00415).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. A. Guseva
    • 1
    • 2
  • D. A. Alentiev
    • 1
  • D. I. Gavrilov
    • 1
    • 2
  • E. V. Bermesheva
    • 1
    • 2
    • 3
  • P. P. Chapala
    • 2
  • E. Sh. Finkelshtein
    • 1
  • M. V. Bermeshev
    • 1
    • 2
    Email author
  1. 1.Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesMoscowRussia
  2. 2.Institute of Fine Chemical Technologies, Russian University of Technology (MIREA)MoscowRussia
  3. 3.Sechenov First Moscow State Medical UniversityMoscowRussia

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