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Polymer Science, Series B

, Volume 61, Issue 5, pp 622–628 | Cite as

Synthesis and Porous Structure of Addition Polymer Based on Dicyclopentadiene

  • A. I. Wozniak
  • E. V. Bermesheva
  • N. N. Gavrilova
  • M. V. BermeshevEmail author
FUNCTIONAL POLYMERS
  • 7 Downloads

Abstract

A simple two-stage scheme is proposed for the synthesis of a new porous polymeric material based on dicyclopentadiene, an industrial product and one of the most accessible derivatives of norbornene. The selective addition polymerization of dicyclopentadiene, a bifunctional monomer, proceeds via opening of only one endocyclic double bond and the subsequent hydrogenation of the synthesized product makes it possible to obtain a saturated polymeric material with a high specific surface area (425 m2/g). The porous structure of the hydrogenated addition polydicyclopentadiene is studied in comparison with a similar polymer before hydrogenation using low-temperature nitrogen adsorption/desorption and X-ray powder diffraction. It is shown that the polymeric material obtained has a high thermal stability.

Notes

FUNDING

This study was performed within the framework of the State Task for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. I. Wozniak
    • 1
  • E. V. Bermesheva
    • 1
    • 2
  • N. N. Gavrilova
    • 3
  • M. V. Bermeshev
    • 1
    • 3
    Email author
  1. 1.Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesMoscowRussia
  2. 2.I. M. Sechenov First Moscow State Medical University of the Ministry of Health of the Russian FederationMoscowRussia
  3. 3.Mendeleev University of Chemical Technology of RussiaMoscowRussia

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