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Polymer Science, Series B

, Volume 61, Issue 5, pp 540–549 | Cite as

Green Chemistry of Polyurethanes: Synthesis, Functional Composition, and Reactivity of Cyclocarbonate-Containing Sunflower Oil Triglycerides—Renewable Raw Materials for New Urethanes

  • M. A. LevinaEmail author
  • D. G. Miloslavskii
  • M. V. Zabalov
  • M. L. Pridatchenko
  • A. V. Gorshkov
  • V. T. Shashkova
  • V. L. Krasheninnikov
  • R. P. Tiger
SYNTHESIS
  • 13 Downloads

Abstract

Epoxy- and cyclocarbonate-containing oligomers are synthesized by oxidizing sunflower oil and subsequent catalytic carbonization via reaction with carbon dioxide. Using mass spectrometry, it is shown that oligomers, which are triglycerides of epoxy- and cyclocarbonate-containing carboxylic acid derivatives, are characterized by a wide distribution over composition, reflecting the entire set of components contained in natural raw materials. It is found that oligomers derived from sunflower oil contain 16 types of triglycerides in various combinations in contrast to 25 types of triglycerides contained in soybean oil-based oligomers. At the same time, the reactivity of both oligomers as the main representatives of renewable plant materials for new urethanes, which is evaluated by studying the n-butylaminolysis model reaction, is approximately the same.

Notes

FUNDING

The work was performed within the framework of the state task (Theme V 45.5, 0082-2014-0015, no. AAAA-A17-117032750201-9) and was supported by the Russian Foundation for Basic Research (project 17-03-00146).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. A. Levina
    • 1
    Email author
  • D. G. Miloslavskii
    • 2
  • M. V. Zabalov
    • 1
  • M. L. Pridatchenko
    • 3
  • A. V. Gorshkov
    • 1
  • V. T. Shashkova
    • 1
  • V. L. Krasheninnikov
    • 1
  • R. P. Tiger
    • 1
  1. 1.Semenov Institute of Chemical Physics, Russian Academy of SciencesMoscowRussia
  2. 2.Kazan National Research Technological UniversityKazanRussia
  3. 3.Talroze Institute of Energy Problems of Chemical Physics, Russian Academy of SciencesMoscowRussia

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