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Polymer Science, Series B

, Volume 61, Issue 5, pp 530–539 | Cite as

Synthesis of Polyesters of Diatomic Phenols and Boric Acid and Their Interaction with Formaldehyde

  • M. A. LenskiyEmail author
  • E. E. Shul’ts
  • D. V. Korabel’nikov
  • A. V. Ozhogin
  • A. N. Novitskiy
POLYCONDENSATION
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Abstract

The interaction of boric acid and diatomic phenols (resorcinol, hydroquinone and bisphenol А) yields boron-containing polyesters whose condensation with formaldehyde affords corresponding poly(methylene esters). The structure of oligomers is studied by IR, 1Н, 13С, and 11В NMR spectroscopy. Vicat softening temperatures of the synthesized compounds are 70–105°С. All oligomers are soluble in alcohol, acetone, and DMF, except poly(methylene esters) based on bisphenol A. The molecular weights of the oligomers based on resorcinol and hydroquinone are within (1.6–4.2) × 103, and soluble diane oligoesters have Mn = (9–14) × 103.

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. A. Lenskiy
    • 1
    • 2
    Email author
  • E. E. Shul’ts
    • 3
  • D. V. Korabel’nikov
    • 1
  • A. V. Ozhogin
    • 1
  • A. N. Novitskiy
    • 1
    • 2
  1. 1.Biysk Technological Institute, Altai State Technical UniversityBiyskRussia
  2. 2.Institute for Problems of Chemical and Energetic Technologies, Siberian Branch, Russian Academy of SciencesBiyskRussia
  3. 3.Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia

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