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Polymer Science, Series B

, Volume 60, Issue 6, pp 708–716 | Cite as

Influence of Viscosity of Compositions Based on Dimethacrylate Esters on Kinetics of Their Photopolymerization Initiated by 9,10-Phenanthrenequinone

  • M. Yu. Zakharina
  • Yu. V. Chechet
  • M. P. Shurygina
  • S. A. ChesnokovEmail author
Polymerization
  • 1 Downloads

Abstract

The kinetics of photopolymerization of compositions based on dimethacrylic oligomers in which the viscosity was varied from 3.1 to 376.7 cSt was investigated (initiator 9,10-phenanthrenequinone) under the influence of visible light. Triethyleneglycol dimethacrylate and dimethacrylates OCM-2 and MDPh-2 were used, as well as solvents methanol and butanol-1. The dependences of the viscosity of dimethacrylate–alcohol compositions on the concentration of components were determined. It was shown that the photoreduction rate of 9,10-phenanthrenequinone in dimethacrylate OCM-2 decreases with the alcohol and acetonitrile addition. It was found that, at the initial stages of the reaction, the dependence of the reduced photopolymerization rate on the initial viscosity of the compositions is described by a saturation curve with the plateau at a viscosity of 80 cSt or more.

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References

  1. 1.
    S. Davidson, Exploring the Science, Technology and Application of UV and EB Curing (SITA Technology Ltd., London, 1999).Google Scholar
  2. 2.
    J. G. Kloosterboer, Adv. Polym. Sci. 84, 1 (1988).CrossRefGoogle Scholar
  3. 3.
    K. S. Anseth, S. M. Newman, and C. N. Bowman, Adv. Polym. Sci. 122, 177 (1995).CrossRefGoogle Scholar
  4. 4.
    C. Decker, Prog. Polym. Sci. 21, 593 (1996).CrossRefGoogle Scholar
  5. 5.
    Y. G. Medvedevskikh, A. R. Kytsya, L. I. Bazylyak, A. A. Turovsky, and G. E. Zaikov, Stationary Kinetics of the Photoinitiated Polymerization (VSP, Utrecht; Boston, 2004).Google Scholar
  6. 6.
    P. J. Bartolo, Stereolithography: Materials, Processes and Applications (Springer-Verlag, New York, 2011).CrossRefGoogle Scholar
  7. 7.
    A. A. Berlin, G. V. Korolev, T. Ya. Kefeli, and Yu. M. Sivergin, Acrylic Oligomers and Related Materials (Khimiya, Moscow, 1983) [in Russian].Google Scholar
  8. 8.
    L. A. Sukhareva, Polyether Coatings. Structure and Porperties (Khimiya, Moscow, 1987) [in Russian].Google Scholar
  9. 9.
    S. N. Mensov and Y. V. Polushtaytsev, Laser Phys. 18 (4), 424 (2008).CrossRefGoogle Scholar
  10. 10.
    V. M. Treushnikov and S. A. Chesnokov, J. Photochem. Photobiol., A 196, 201 (2008).CrossRefGoogle Scholar
  11. 11.
    N. Moszner and T. Hirt, J. Polym. Sci., Part A: Polym. Chem. 50, 4369 (2012).CrossRefGoogle Scholar
  12. 12.
    J. G. Leprince, W. M. Palin, M. A. Hadis, J. Devaux, and G. Leloup, Dent. Mater. 29, 139 (2013).CrossRefGoogle Scholar
  13. 13.
    S. A. Chesnokov, M. V. Arsenyev, R. S. Kovylin, N. A. Lenshina, M. A. Baten’kin, A. I. Poddel’sky, and G. A. Abakumov, Appl. Organomet. Chem. 31 (2), e3553 (2017).CrossRefGoogle Scholar
  14. 14.
    M. Yu. Zakharina, V. B. Fedoseev, Yu. V. Chechet, S. A. Chesnokov, and A. S. Shaplov, Polym. Sci., Ser. B 59, 665 (2017).CrossRefGoogle Scholar
  15. 15.
    M. A. Baten’kin, A. N. Konev, S. N. Mensov, and S. A. Chesnokov, Polym. Sci., Ser. A 53, 558 (2011).CrossRefGoogle Scholar
  16. 16.
    S. A. Chesnokov, M. Y. Zakharina, A. S. Shaplov, E. I. Lozinskaya, I. A. Malyshkina, G. A. Abakumov, F. Vidal, and Yu. S. Vygodskii, J. Polym. Sci., Part A: Polym. Chem. 48, 2388 (2010).CrossRefGoogle Scholar
  17. 17.
    C. A. Chesnokov, V. K. Cherkasov, G. A. Abakumov, O. N. Mamysheva, Yu. V. Chechet, and V. I. Nevodchikov, Russ. Chem. Bull. 50, 2366 (2001).CrossRefGoogle Scholar
  18. 18.
    A. A. Berlin, T. Ya. Kefeli, and G. V. Korolev, Polyesteracrylate (Nauka, Moscow, 1967) [in Russian].Google Scholar
  19. 19.
    J. Gordon and R. A. Ford, The Chemist’s Companion (AWiley Intersci. Publ., J. Wiley and Sons, New York; London; Sydney; Toronto, 1972).Google Scholar
  20. 20.
    V. I. Arulin and L. I. Efimov, Tr. Khim. Khim. Tekhnol., No. 2, 74 (1970).Google Scholar
  21. 21.
    S. Patai, The Chemistry of the Quinonoid Compounds (Wiley, London; New York; Sydney; Toronto, 1974).Google Scholar
  22. 22.
    S. A. Chesnokov, V. K. Cherkasov, G. A. Abakumov, O. N. Mamysheva, M. Yu. Zakharina, N. Yu. Shushunova, Yu. V. Chechet, and V. A. Kuropatov, Polym. Sci., Ser. B 56, 11 (2014).CrossRefGoogle Scholar
  23. 23.
    M. P. Shurygina, Yu. A. Kurskii, S. A. Chesnokov, and G. A. Abakumov, Tetrahedron 64, 1459 (2008).CrossRefGoogle Scholar
  24. 24.
    M. P. Shurygina, Yu. A. Kurskii, N. O. Druzhkov, S. A. Chesnokov, G. A. Abakumov, High Energy Chem. 44, 234 (2010).CrossRefGoogle Scholar
  25. 25.
    E. Andrzejewska, L. Linden, and J. F. Rabek, Macromol. Chem. Phys. 199, 441 (1998).CrossRefGoogle Scholar
  26. 26.
    A. I. Kryukov, V. P. Sherstyuk, and I. I. Dilung, Electron Phototrasnfer and its Application (Naukova Dumka, Kiev, 1982) [in Russian].Google Scholar
  27. 27.
    M. P. Shurygina, S. A. Chesnokov, and G. A. Abakumov, High Energy Chem. 50, 196 (2016).CrossRefGoogle Scholar
  28. 28.
    M. P. Shurygina, S. A. Chesnokov, and G. A. Abakumov, High Energy Chem. 50, 356 (2016).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. Yu. Zakharina
    • 1
  • Yu. V. Chechet
    • 1
  • M. P. Shurygina
    • 1
  • S. A. Chesnokov
    • 1
    Email author
  1. 1.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussia

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