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Polymer Science, Series B

, Volume 60, Issue 6, pp 717–726 | Cite as

Oxidative Polymerization of 3,6-Dianiline-2,5-dichlorobenzoquinone and Its Copolymerization with Aniline

  • S. G. KiselevaEmail author
  • A. V. Orlov
  • G. N. Bondarenko
  • G. P. Karpacheva
Polymerization

Abstract

The oxidative polymerization of 3,6-dianiline-2,5-dichlorobenzoquinone is studied for the first time and it is shown that its reactivity in oxidation processes is higher than that of aniline. The influence of concentration, reagent ratio, and the acidity and temperature of reaction solution on the oxidation reaction is investigated. The specific features of polymerization of 3,6-dianiline-2,5-dichlorobenzoquinone determined by the presence of a chloranil substituent at the nitrogen atom are revealed. Poly(3,6-dianiline-2,5-dichlorobenzoquinone) has a highly ordered supramolecular structure. The copolymerization of 3,6-dianiline-2,5-dichlorobenzoquinone with aniline is studied, and it is found that the reaction kinetics and the degree of copolymer oxidation are determined by aniline content in the monomer mixture.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. G. Kiseleva
    • 1
    Email author
  • A. V. Orlov
    • 1
  • G. N. Bondarenko
    • 1
  • G. P. Karpacheva
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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