Polymer Science, Series B

, Volume 60, Issue 6, pp 754–759 | Cite as

Composition and Microstructure of Norbornene–Ethylene Copolymers

  • V. I. BykovEmail author
  • T. A. Butenko
Functional Polymers


The comparative analysis of the composition and microstructure of norbornene–ethylene copolymers obtained with the use of metallocomplex catalysts on the basis of nickel phosphorylide, zirconocenes, and titanocenes is carried out. It is shown that, depending on the structure of nickel phosphorylide complex, alternating copolymers or copolymers involving short blocks (diads, triads) of norbornane units are formed.


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  1. 1.
    M. S. Kitai, M. M. Nazarov, D. A. Sapozhnikov, V. I. Bykov, M. V. Bermeshev, S. A. Bulgakova, and B. F. Shklyaruk, Radiophys. Quantum Electron. (Engl. Transl.) 57, 881 (2015).CrossRefGoogle Scholar
  2. 2.
    K. Nielsen, H. K. Rasmussen, A. J. L. Adam, P. C.M. Planken, O. Bang, and P. U. Jepsen, Opt. Express 17, 8592 (2009).CrossRefGoogle Scholar
  3. 3.
    A. W. Anderson, W. Del, and N. G. Mercking, US Patent No. 2799668 (1957).Google Scholar
  4. 4.
    E. Brauer, H. Wiegleb, and M. Helmstedt, Polym. Bull. 15, 551 (1986).CrossRefGoogle Scholar
  5. 5.
    E. Brauer, C. Wild, and H. Wiegleb, Polym. Bull. 18, 73 (1987).CrossRefGoogle Scholar
  6. 6.
    W. Kaminsky, M. Arndt, and A. Bark, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 32, 467 (1991).Google Scholar
  7. 7.
    I. Tritto, L. Boggioni, and D. R. Ferro, Coord. Chem. Rev. 250, 212 (2006).CrossRefGoogle Scholar
  8. 8.
    K. L. Makovetsky, E. Sh. Finkelshtein, V. I. Bykov, A. Kh. Bagdasaryan, B. L. Goodall, and L. F. Rhodes, US Patent No. 5929181 (1999).Google Scholar
  9. 9.
    K. L. Makovetskii, V. I. Bykov, and E. Sh. Finkel’shtein, Kinet. Catal 47, 241 (2006).CrossRefGoogle Scholar
  10. 10.
    K. H. Bergström, J. Polym. Sci., Part A: Polym. Chem. 36, 1634 (1998).CrossRefGoogle Scholar
  11. 11.
    M. Blochowiak, T. Pakula, H.-J. Butt, M. Bruch, and G. Floudas, J. Chem. Phys. 124, 134903 (2006).CrossRefGoogle Scholar
  12. 12.
    W. Kaminsky, O. Sperber, and R. Werner, Coord. Chem. Rev. 250, 110 (2006).CrossRefGoogle Scholar
  13. 13.
    D. Ruchatz and G. Fink, Macromolecules 31, 4681 (1998).CrossRefGoogle Scholar

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© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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