Glass Physics and Chemistry

, Volume 44, Issue 5, pp 428–432 | Cite as

Intercalation of Methylamine into the Protonated Forms of Layered Perovskite-Like Oxides HLnTiO4 (Ln = La and Nd)

  • O. I. SilyukovEmail author
  • S. A. Kurnosenko
  • I. A. Zvereva


New hybrid organic-inorganic derivatives HLnTiO4 · CH3NH2 (Ln = La and Nd) are obtained via the intercalation of methylamine into the interlayer space of protonated layered perovskite-like titanates HLnTiO4. The existence of three stable methylamine derivatives, namely, α-, β-, and γ-forms, is found for each of the titanates. The thermal stability of the obtained intercalation products is studied and their structural parameters are determined.


layered titanate methylamine intercalation organic-inorganic compounds hydrothermal microwave synthesis 


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • O. I. Silyukov
    • 1
    Email author
  • S. A. Kurnosenko
    • 1
  • I. A. Zvereva
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

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