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Russian Journal of Organic Chemistry

, Volume 55, Issue 6, pp 890–893 | Cite as

Synthesis of 3-Aroyl-2-(polyfluoroalkyl)quinoxalines and 3-Aroyl-2-(polyfluoroalkyl)benzo[g]quinoxalines from Lithium 3-(Fluoroalkyl)-1,3-diketonates

  • V. I. FilyakovaEmail author
  • N. S. Boltacheva
  • V. N. Charushin
Short Communications
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Abstract

A one-pot procedure has been developed for the synthesis of 3-aroyl-2-(polyfluoroalkyl)quinoxalines and 3-aroyl-2-(polyfluoroalkyl)benzo[g]quinoxalines by nitrosation of lithium 3-(polyfluoroalkyl)-1,3-diketonates and subsequent reaction with benzene-1,2-diamine or naphthalene-2,3-diamine, respectively.

Keywords

fluorinated lithium 1,3-diketonates benzene-1,2-diamine naphthalene-2,3-diamine 3-benzoyl-2-polyfluoroalkylquinoxalines 3-aroyl-2-polyfluoroalkylbenzo[g]quinoxalines 

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Notes

Acknowledgments

This study was performed using the facilities of the “Spectroscopy and Analysis of Organic Compounds” joint center (Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences).

Funding

This study was performed under financial support by the Russian Foundation for Basic Research (project no. 18-03-00112 A).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. I. Filyakova
    • 1
    Email author
  • N. S. Boltacheva
    • 1
  • V. N. Charushin
    • 1
  1. 1.Postovskii Institute of Organic Synthesis, Ural BranchRussian Academy of SciencesYekaterinburgRussia

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