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Russian Journal of Organic Chemistry

, Volume 55, Issue 6, pp 883–885 | Cite as

Oxidative Cyclization of Lithium 4-Ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate

  • N. S. Boltacheva
  • P. A. Slepukhin
  • V. I. FilyakovaEmail author
  • V. N. Charushin
Short Communications
  • 8 Downloads

Abstract

Diethyl 2,5-dihydroxy-2,5-bis(trifluoromethyl)tetrahydrofuran-3,4-dicarboxylate has been synthesized for the first time by reaction of lithium 4-ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate with manganese(III) acetate. The structure of its (2S*3S*4S*5S*) stereoisomer has been confirmed by X-ray analysis.

Keywords

lithium 4-ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate manganese(III) acetate diethyl 2,5-dihydroxy-2,5-bis(trifluoromethyl)tetrahydrofuran-3,4-dicarboxylate crystal structure X-ray analysis 

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Notes

Acknowledgments

This study was performed using the facilities of the “Spectroscopy and Analysis of Organic Compounds” joint center (Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences).

Funding

This study was performed in the framework of state assignment no. AAAA-A19-119011790132-7.

References

  1. 1.
    Badanyan, Sh.O., Melikyan, G.G., and Mkrtchyan, D.A., Russ. Chem. Rev., 1989, vol. 58, p. 286. doi  https://doi.org/10.1070/RC1989v058n03ABEH003440 CrossRefGoogle Scholar
  2. 2.
    Slepukhin, P.A., Boltacheva, N.S., Filyakova, V.I., and Charushin, V.N., Russ. Chem. Bull., Int. Ed., 2009, vol. 58, p. 1228. doi  https://doi.org/10.1007/s11172-009-0159-3 CrossRefGoogle Scholar
  3. 3.
    Bräuer, G., Handbuch der Präparativen anorganischen Chemie, Stuttgart: Enke, 1981. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1985, vol. 5, p. 1693.Google Scholar
  4. 4.
    Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008. vol. 64, p. 112. doi  https://doi.org/10.1107/S0108767307043930 CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • N. S. Boltacheva
    • 1
  • P. A. Slepukhin
    • 1
  • V. I. Filyakova
    • 1
    Email author
  • V. N. Charushin
    • 1
  1. 1.Postovskii Institute of Organic Synthesis, Ural BranchRussian Academy of SciencesYekaterinburgRussia

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