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Russian Journal of Organic Chemistry

, Volume 55, Issue 5, pp 734–736 | Cite as

Reaction of N,N′-Methylenebis(trifluoromethanesulfonamide) with Styrene under Oxidative Conditions

  • M. Yu. Moskalik
  • V. V. Astakhova
  • A. S. Ganin
  • B. A. ShainyanEmail author
Short Communications
  • 7 Downloads

Abstract

The reaction of N,N′-methylenebis(trifluoromethanesulfonamide) with styrene in the oxidative system t-BuOCl/NaI affords triflamide, 2-iodo-1-phenylethanol, N,N′-bis(trifluoromethanesulfonyl)urea, and the product of styrene bistriflamidation. The mechanism is proposed involving hydrolysis and oxidation of the starting N,N′-methylenebis(trifluoromethanesulfonamide).

Keywords

N,N′-methylenebis(trifluoromethanesulfonamide) oxidation styrene triflamidation oxyiodination 

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Notes

Acknowledgments

The work was performed using the equipment of the Baikal Analytical Center for Collective Use, Siberian Branch, Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. Yu. Moskalik
    • 1
  • V. V. Astakhova
    • 1
  • A. S. Ganin
    • 1
  • B. A. Shainyan
    • 1
    Email author
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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