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Russian Journal of Organic Chemistry

, Volume 55, Issue 5, pp 646–649 | Cite as

Synthesis of Novel Exocyclic Allenes with a Norbornene Fragment

  • A. F. Mukhametyanova
  • I. M. SakhautdinovEmail author
  • T. R. Nugumanov
  • M. S. Yunusov
Article
  • 6 Downloads

Abstract

N-Substituted amino acids with a norbornene fragment were synthesized by the direct fusion of amino acids with endic anhydride at 150°C. The synthesized compounds were used for one-pot synthesis of novel stable allenes with an exocyclic cumulene group derived from l-phenyl-3-(triphenylphosphoranylidene)-pyrrolidine-2,5-dione has been carried out.

Keywords

allenes norbornenes exocyclic allenoates Arndt-Eistert reaction phosphorus ylides amino acids endic anhydride 

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Notes

Acknowledgments

The spectral part of the research was performed on the equipment of the Center for Collective Use, Ufa Institute of Chemistry, Russian Academy of Sciences (RAS).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. F. Mukhametyanova
    • 1
  • I. M. Sakhautdinov
    • 1
    Email author
  • T. R. Nugumanov
    • 1
  • M. S. Yunusov
    • 1
  1. 1.Ufa Institute of Chemistry, Ufa Research CenterRussian Academy of Sciences (RAS)Ufa, Republic of BashkortostanRussia

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