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Russian Journal of Organic Chemistry

, Volume 55, Issue 1, pp 101–107 | Cite as

New Tetracyclic Spiro-1,2,4-trioxolanes (Ozonides). Synthesis and Mass Spectrometric Study

  • T. I. AkimovaEmail author
  • V. G. Rybin
  • O. A. Soldatkina
Article
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Abstract

New tetracyclic dispiro-1,2,4-trioxolanes (ozonides) were synthesized by reactions of 5–7-membered alicyclic 1,5-diketones with 30% hydrogen peroxide in diethyl ether or ethanol in the presence of boron trifluoride-diethyl ether complex or a strong mineral acid (HCl, H2SO4, HClO4). Mass spectrometric study of the title compounds under atmospheric pressure chemical ionization revealed specificity of fragment ion decomposition with respect to the ring size, which makes it possible to identify such compounds by their mass spectra.

Keywords

alicyclic 1,5-diketones hydrogen peroxide spiro-1,2,4-trioxolanes tetracyclic ozonides mass spectrometry atmospheric pressure chemical ionization quasi-molecular ions 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • T. I. Akimova
    • 1
    Email author
  • V. G. Rybin
    • 2
  • O. A. Soldatkina
    • 1
  1. 1.Far Eastern Federal UniversityVladivostokRussia
  2. 2.Zhirmunskii Institute of Marine Biology, Far Eastern BranchRussian Academy of SciencesVladivostokRussia

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