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Russian Journal of Organic Chemistry

, Volume 55, Issue 1, pp 87–92 | Cite as

Trifluoroacetylation of N-Substituted 1H-1,2-Diazaphenalenes of the Naphthalene and Acenaphthene Series

  • N. I. OmelichkinEmail author
  • L. G. Minyaeva
  • M. S. Korobov
  • G. S. Borodkin
  • L. G. Kuz’mina
  • V. V. Mezheritskii
Article
  • 8 Downloads

Abstract

The acylation of N-substituted 3-methyl-1H-1,2-diazaphenalenes of the naphthalene and acenaphthene series with trifluoroacetic anhydride gave mono- and diacylated products. Despite the presence of a bulky substituent on the pyrrole type nitrogen atom, the trifluoroacetyl group entered the peri position with respect to that substituent. The product structure was confirmed by X-ray analysis.

Keywords

1,2-diazaphenalenes electrophilic substitution trifluoroacetylation X-ray analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • N. I. Omelichkin
    • 1
    Email author
  • L. G. Minyaeva
    • 1
  • M. S. Korobov
    • 1
  • G. S. Borodkin
    • 1
  • L. G. Kuz’mina
    • 2
  • V. V. Mezheritskii
    • 1
  1. 1.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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