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Russian Journal of Organic Chemistry

, Volume 55, Issue 1, pp 25–41 | Cite as

Synthesis of Nanostructured Organosilicon Luminophores Based on Phenyloxazoles

  • M. S. Skorotetcky
  • O. V. Borshchev
  • G. V. Cherkaev
  • S. A. PonomarenkoEmail author
Article
  • 2 Downloads

Abstract

A series of nanostructured organosilicon luminophores (NOLs) composed of a central 1,4-bis(5-phenyl-1,3-oxazol-2-yl)benzene (POPOP) acceptor chromophore and various peripheral p-terphenyl and 2,5-diphenyl-1,3-oxazole donor fragments have been synthesized for the first time using van Leusen reaction and direct palladium-catalyzed C-arylation of oxazole ring. Due to different functionalities of the silicon branching centers, NOLs with different donor-acceptor ratios have been obtained. The synthesized structures are expected to possess good optical characteristics for use in photonics and optoelectronics.

Keywords

direct C-arylation van Leusen reaction phenyloxazole arylsilane luminophore terphenyl POPOP 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. S. Skorotetcky
    • 1
  • O. V. Borshchev
    • 1
  • G. V. Cherkaev
    • 1
  • S. A. Ponomarenko
    • 1
    • 2
    Email author
  1. 1.Enikolopov Institute of Synthetic Polymeric MaterialsRussian Academy of SciencesMoscowRussia
  2. 2.Faculty of ChemistryMoscow State UniversityMoscowRussia

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