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Russian Journal of Organic Chemistry

, Volume 54, Issue 11, pp 1722–1724 | Cite as

Example of a Facile Substitution of the Hydroxy Group Due to the Anchimeric Assistance of Selenium

  • E. O. Kurkutov
  • V. A. Potapov
  • S. V. AmosovaEmail author
Short Communications
  • 3 Downloads

Abstract

Bis(2-bromo-3-hydroxypropyl) selenide was synthesized in quantitative yield by the reaction od selenium bromide with allyl alcohol. The product undergoes facile methanolysis at room temperature, which is accompanied by a rearrangement and involves substitution of bromine and hydroxy groups, located β to the selenium atom, to form bis(1,3-dimethoxypropan-2-yl) selenide and (3-hydroxy-2-methoxypropyl)(1,3-dimethoxypropan-2-yl) selenide.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. O. Kurkutov
    • 1
  • V. A. Potapov
    • 1
  • S. V. Amosova
    • 1
    Email author
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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