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Russian Journal of Organic Chemistry

, Volume 54, Issue 11, pp 1643–1651 | Cite as

Synthesis and Transformations of 2-(Adamantan-1-yl)aziridine

  • M. V. LeonovaEmail author
  • N. V. Belaya
  • M. R. Baimuratov
  • Yu. N. Klimochkin
Article
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Abstract

Mono- and disubstituted aziridines derived from sterically hindered olefins of the adamantane series are synthesized. The opening of the aziridine ring under the action of acids is quite a regio- and stereoselective process. Depending on the nature of the nucleophilic agent, the opening of the 2,2-disubstituted aziridine ring can occur by the SN1 or SN2 mechanism.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. V. Leonova
    • 1
    Email author
  • N. V. Belaya
    • 1
  • M. R. Baimuratov
    • 1
  • Yu. N. Klimochkin
    • 1
  1. 1.Samara State Technical UniversitySamaraRussia

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