Russian Journal of Applied Chemistry

, Volume 92, Issue 7, pp 1013–1019 | Cite as

Study of Structural Changes in LiNi0.8Co0.1Mn0.1O2 Cathode Material for Lithium-Ion Batteries by X-Ray Diffraction Analysis in the In Situ Mode

  • P. A. Novikov
  • A. E. KimEmail author
  • K. A. PushnitsaEmail author
  • Wang Quingsheng
  • M. Yu. Maksimov
  • A. A. Popovich
Applied Electrochemistry and Metal Corrosion Protection


Structural changes in a promising cathode material LiNi0.8Co0.1Mn0.1O2 for lithium-ion batteries were in situ studied by X-ray diffraction analysis in the course of electrochemical reactions. The Rietveld method and TOPAS 5 software package were used to examine changes in the unit cell parameters of LiNi0.8Co0.1Mn0.1O2 and the reasons for these changes. It was found that the unit cell volume increases by 2% relative to the discharged state (2.7 V) upon charging to 4.2 V.


Li-ion X-ray diffraction analysis cathode material structural changes NCM811 LiNi0.8Co0.1Mn0.1O2 


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  1. 1.
    Dunn, B., Kamath, H., and Tarascon, J.-M., Science, 2011, vol 334, no. 6058, pp. 928–935.CrossRefPubMedPubMedCentralGoogle Scholar
  2. 2.
    Mahes, D.B. and Colm, O.D., Phys. Chem. Chem. Phys., 2015, vol 17, no. 7, pp. 4799–4844.CrossRefGoogle Scholar
  3. 3.
    Nitta, N., Wu, F., Lee, J.-T., and Yushin, G., Mater. Today, 2015, vol 18, no. 5, pp. 252–264.CrossRefGoogle Scholar
  4. 4.
    Popovich, A.A., Novikov, P.A., Silin, A.O., Razumov, N.G., and Wang Qingsheng, Russ. J. Appl. Chem., 2014, vol 87, no. 9, pp. 1268–1273.CrossRefGoogle Scholar
  5. 5.
    Popovich, A.A., Maximov, M.Y., Silin, A.O., Novikov, P.A., Koshtyal, Y.M., and Rumyantsev, A.M., Russ. J. Appl. Chem., 2016, vol 89, no. 10, pp. 1607–1611.CrossRefGoogle Scholar
  6. 6.
    Wang Qingsheng, Popovich, A.A., Zhdanov, V.V., Novikov, P.A., Maximov, M.Y., Koshtyal, Y.M., Rumyantsev, A.M., and Silin, A.O., Russ. J. Appl. Chem., 2014, vol 91, no. 1, pp. 60–61.Google Scholar
  7. 7.
    Ghassan, Z., Rodolfo, D.-L., Carvaho, M., and Pasaoglu, G., Renewable Sustainable Energy Rev., 2018, vol 89, pp. 292–308.CrossRefGoogle Scholar
  8. 8.
    Sun, Y.-K., Myung, S.-T., Park, B.-C., Prakash, J., Belharouak, I., and Amine, K., Nat. Mater., 2009, vol. 8, no. 4, pp. 320–324.CrossRefPubMedGoogle Scholar
  9. 9.
    Kang, S.-H., Kim, J., Stoll, M.E., Abraham, D., Sun, Y.-K., and Amine, K., J. Power Sources, 2012, vol 112, no. 1, pp. 41–48.CrossRefGoogle Scholar
  10. 10.
    Sun, Y.-K., Ouyang, C., Wang, Z., Huang, X., Chen, L., J. Electrochem. Soc., 2004, vol 151, no. 4, p. A504.CrossRefGoogle Scholar
  11. 11.
    Sun, J., Li, J., Zhou, T., Yang, K., Wei, S., Tang, N., Dang, N., Li, H., Qiu, X., and Chen, L., Nano Energy, 2016, vol 27, pp. 313–319.CrossRefGoogle Scholar
  12. 12.
    Wu, B., Lochala, J., Taverne, T., and Xiao, J., Nano Energy, 2017, vol 40, pp. 34–41.CrossRefGoogle Scholar
  13. 13.
    Mohanty, D., Kalnaus, S., Meisner, R.A., Rhodes, K.J., Li, J., Payzant, E.A., Wood III, D.L., and Claus, D., J. Power Sources, 2013, vol 229, pp. 239–248.CrossRefGoogle Scholar
  14. 14.
    Hausbrand, R., Cherkashinin, G., Ehrenberg, H., Gröting, M., Albe, K., Hess, C., and Jaegermann, W., Mater. Sci. Eng., 2015, vol 192, pp. 3–25.CrossRefGoogle Scholar
  15. 15.
    Nazarov, D.V., Maximov, M.Yu., Popovich, A.A., Novikov, P.A., Silin, A.O., Smirnov, V.M., Bobrysheva, N.P., Osmolovskaya, O.M., Osmolovsky, M.G., and Rumyantsev, A.M., J. Vac.Sci. Technol., A, 2017, vol 35, no. 1, pp. 1–11.CrossRefGoogle Scholar
  16. 16.
    Makhonina, E.V., Maslennikova, L.S., Volkov, V.V., Medvedeva, A.E., Rumyantsev, A.M., Koshtyal, Y.M., Maximov, M.Y., Pervov, V.S., and Eremenko, I.L., Appl. Surf. Sci., 2019, vol 474, pp. 25–33.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • P. A. Novikov
    • 1
    • 2
  • A. E. Kim
    • 1
    • 2
    Email author
  • K. A. Pushnitsa
    • 1
    • 3
    Email author
  • Wang Quingsheng
    • 1
    • 2
  • M. Yu. Maksimov
    • 2
  • A. A. Popovich
    • 2
  1. 1.Zheang Changxing CHN/RUS New Energy and Material Technology Research InstituteZhejiang, Changxing CountyChina
  2. 2.Peter the Great St. Petersburg Polytechnic UniversitySt. PetersburgRussia
  3. 3.St. Petersburg State Technological Institute (Technical University)St. PetersburgRussia

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