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Russian Journal of Applied Chemistry

, Volume 92, Issue 5, pp 620–624 | Cite as

Biomass Conversion Products as Steel Corrosion Inhibitors

  • V. I. MishurovEmail author
  • E. N. Shubina
  • V. A. Klushin
  • A. A. Chizhikova
  • V. P. Kashparova
  • A. G. Berezhnaya
Applied Electrochemistry and Metal Corrosion Protection
  • 9 Downloads

Abstract

By-products formed in the conversion of vegetable biomass (multicomponent tar) were studied in comparison with the target products of the process (5-hydroxymethylfurfural, 2,5-diformylfuran) as inhibitors of corrosion of low-carbon steel in sulfuric acid at temperatures of 25-90°C. The gravimetric method was used to determine the inhibiting effect of additives. All these additives exhibit medium protective effects in an acid medium, with the degree of protection in 1 M sulfuric acid at room temperature exceeding 80%. The potentiody-namic polarization method was used to determine the influence exerted by the additives on partial reactions of the corrosion process. It was shown that the tar and 2,5-diformylfuran behave as additives of the cathodic type, and 5-hydroxymethylfurfural, as that of a mixed type. Temperature-kinetic calculations were used to determine the mechanism of action of the inhibitors. The corrosion process occurs in the presence of additives predominantly under the kinetic control.

Keywords

corrosion low-carbon steel inhibitor biomass conversion furan derivatives. capacity 

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References

  1. 1.
    Belousova, N.A., Grigor'ev, V.P., Plekhanova, E.V., and Shpan'ko, S.P., Korroz.: Mater., Zashch., 2015, no. 8, pp. 13–17.Google Scholar
  2. 2.
    Khaidarova, G.R., Islamutdinova, A.A., Dmitriev, Yu. K., Sidorov, G.M., and Ivanov, A.N., Neftegaz. Delo, 2015, vol. 13, no. 4, pp. 163–168.Google Scholar
  3. 3.
    Chernyshev, V.M., Kravchenko, O.A., and Ananikov, V.P., Russ. Chem. Rev., 2017, vol. 86, no. 5, pp. 357–387.CrossRefGoogle Scholar
  4. 4.
    Liu, B. and Zhang, Z., ChemSusChem, 2016, vol. 9, no. 16, pp. 2015–2036.CrossRefGoogle Scholar
  5. 5.
    Kashparova, V.P., Cher nyshev, V.M., Khokhlova, E.A., Galkin, K.I., and Ana nikov, V.P., Russ. Chem. Bull., 2015, vol. 64, no. 5, pp. 1069–1073.CrossRefGoogle Scholar
  6. 6.
    Klushin, V.A., Kashpa rova, V.P., Kravchenko, O.A., Smirnova, N.V., Cherny shev, V.M., Ananikov, V.P., Galkin, K.I., and Krivodae va, E.A., Russ. J. Org. Chem., 2016, vol. 52, no. 6, pp. 767–771.CrossRefGoogle Scholar
  7. 7.
    Dutta, S., De, S., and Saha, B., Biomass Bioenergy, 2013, vol. 55, pp. 355–369.CrossRefGoogle Scholar
  8. 8.
    Van Putten, R.-J., Van Der Waal, J.C., De Jong, E., Rasrendra, C.B., Heeres, H.J., and De Vries, J.G., Chem. Rev., 2013, vol. 113, no. 3, pp. 1499–1597.CrossRefGoogle Scholar
  9. 9.
    Kashparov, I.I., Klushin, V.A., Vinokurov, I.P., Zuben-ko, A.F., Kashparova, V.P., and Smirnova, N.V., Al'tern. Energ. Ekol., 2017, nos. 19–21, pp. 116–125.Google Scholar
  10. 10.
    Chernysheva, D.V., Chus, Yu. A., Klushin, V. A., Las-tovina, T.A., Pudova, L.S., Smirnova, N.V., Kravchen-ko, O.A., Chernyshev, V.M., and Ananikov, V.P., Sustainable Utilization of Biomass Refinery Wastes for Accessing Activated Carbons and Supercapacitor Electrode Materials, ChemSusChem, 2018. https://onlinelibrary.wiley.com/doi/10.1002/cssc.201801757 (Cited: 15 Sept., 2018).Google Scholar
  11. 11.
    Machnikova, E., Whitmire, K.H., and Hackerman, N., Electrochim. Acta, 2008, vol. 53, no. 20, pp. 6024–6032.CrossRefGoogle Scholar
  12. 12.
    Khaled, K.F., J. Electrochem. Soc., 2010, vol. 157, no. 3, pp. C116–C124.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. I. Mishurov
    • 1
    Email author
  • E. N. Shubina
    • 1
  • V. A. Klushin
    • 2
  • A. A. Chizhikova
    • 2
  • V. P. Kashparova
    • 2
  • A. G. Berezhnaya
    • 3
  1. 1.Don State Technical UniversityRostov-on-DonRussia
  2. 2.Platov South-Russian State Polytechnic University (NPI)Novocherkassk, Rostov-on-Don oblastRussia
  3. 3.Southern Federal UniversityRostov-on-DonRussia

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