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Russian Journal of Applied Chemistry

, Volume 91, Issue 11, pp 1799–1804 | Cite as

Use of Vanadium-Containing Slime for Preparing Cathodes for Lithium-Ion Current Sources

  • M. S. ShchelkanovaEmail author
  • G. Sh. Shekhtman
  • A. A. Pankratov
Applied Electrochemistry and Metal Corrosion Protection
  • 2 Downloads

Abstract

Crude vanadium-containing dump slimes can be used as a raw material for preparing lithium vanadium oxides suitable as cathode materials for lithium-ion chemical current sources. A simple procedure for preparing LiV3O8 from the slime was suggested. The synthesized compound was characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and synchronous thermal analysis. The material prepared from vanadium-containing dump slimes has uniform microstructure and high electronic conductivity of the order of 1.4 × 10–2 S cm–1; it is thermally stable in the interval 30–550°С and capable of intercalation/deintercalation of lithium ions in its structure in the course of cycling in lithium-ion current sources.

Keywords

lithium current sources cathode materials production waste processing lithium vanadium oxides electrical conductivity thermal analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. S. Shchelkanova
    • 1
    Email author
  • G. Sh. Shekhtman
    • 1
  • A. A. Pankratov
    • 1
  1. 1.Institute of High-Temperature ElectrochemistryUral Branch, Russian Academy of SciencesYekaterinburgRussia

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