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Russian Journal of Applied Chemistry

, Volume 91, Issue 11, pp 1750–1757 | Cite as

Effect of 1-Butanol on the Contrast of Photopolymerizing Compounds Based on Dimethacrylate Esters

  • M. Yu. Zakharina
  • Yu. V. Chechet
  • N. Yu. Shushunova
  • S. A. ChesnokovEmail author
  • G. A. Abakumov
Macromolecular Compounds and Polymeric Materials
  • 5 Downloads

Abstract

The kinetics of visible-light-induced photopolymerization of dimethacrylate derived from phthalic acid, oligo(carbonate dimethacrylate), and triethylene glycol dimethacrylate (MDF-2, OKM-2, and TGM-3, respectively) in the bulk and in the presence of 10–30 wt % 1-butanol and of 9,10-phenanthrenequinone as initiator was studied. The illuminance in the reaction zone was varied from 10 to 40 klx. Introduction of 10 wt % 1-butanol into dimethacrylates of grades MDF-2 and OKM-2 does not alter their photopolymerization kinetics, and a further increase in the alcohol concentration leads to a decrease in the photopolymerization rate. Addition of 10 wt % and larger amounts of 1-butanol to dimethacrylate of grade TGM-3 makes the dependence of the photopolymerization rate at 1% monomer conversion and of the time of reaching 1% monomer conversion on the actinic radiation intensity considerably more pronounced.

Keywords

dimethacrylates 1-butanol 9,10-phenanthrenequinone photopolymerization conversion contrast 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. Yu. Zakharina
    • 1
  • Yu. V. Chechet
    • 1
  • N. Yu. Shushunova
    • 1
  • S. A. Chesnokov
    • 1
    Email author
  • G. A. Abakumov
    • 1
  1. 1.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussia

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