Advertisement

Russian Journal of Applied Chemistry

, Volume 91, Issue 10, pp 1701–1710 | Cite as

An Effect of a Support Nature and Active Phase Morphology on Catalytic Properties of Ni-Containing Catalysts in Hydrogenation of Biphenyl

  • M. M. Chernova
  • P. P. Minayev
  • Ye. A. Martynenko
  • Al. A. Pimerzin
  • Yu. V. Yeremina
  • S. P. Verevkin
  • A. A. PimerzinEmail author
Catalysis
  • 12 Downloads

Abstract

Ni/Sup catalysts were prepared, where SBA-15, γ-Al2O3, SiO2 were used as supports (Sup). The synthesized catalysts were investigated by the methods of low-temperature nitrogen adsorption, temperatureprogrammed reduction (TPR), and high-resolution transmission electron microscopy. The catalytic properties of the prepared catalysts were tested in liquid phase hydrogenation of biphenyl under conditions of a flow installation at temperatures of 60–100°C, pressure of 4 MPa, volumetric feed rate of 4–10 h–1 and H2: feed ratio of 1500 nM.. A 1 wt % solution of biphenyl in heptane,, as a model mixture, was used. It has been established that the activity of nickel hydrogenation catalysts depends on the nickel content and the type of support. The activity of supported nickel catalysts decreases in the series Ni-12/SBA-15 > Ni-12/SiO2 >> Ni-12/Al2O3. The kinetic characteristics of the biphenyl hydrogenation reaction were determined: the rate constants and activation energy for the hydrogenation of the first and second aromatic rings of the substrate molecule.

Keywords

biphenyl hydrogenation Ni-containing catalysts SBA-15 Al2O3 SiO2 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Geburtig, D., Preuster, P., Bosmann, A., Muller, K., and Wasserscheid, P., Int. J. Hydrogen Energy. 2016, no. 41, pp. 1010–1017.CrossRefGoogle Scholar
  2. 2.
    Preuster, P., Papp, C., and Wasserscheid, P., Accounts Chem. Res., 2017, vol. 50, no. 1, pp. 74–85.CrossRefGoogle Scholar
  3. 3.
    He, T., Pei, Q., and Chen, P., J. Energy Chem., 2015, vol. 24, pp. 587–594.CrossRefGoogle Scholar
  4. 4.
    Stanislaus, A., and Cooper, B.H., Catal. Rev.—Sci. Eng., 1994, vol. 36, pp. 75–123.CrossRefGoogle Scholar
  5. 5.
    Castano, P., Van Herk, D., Kreutzer, M.T., Moulijn, J.A., and Makkee, M., Appl. Catal. B, 2009, vol. 88, pp. 213–223.CrossRefGoogle Scholar
  6. 6.
    Kalenchuk, A.N., Bogdan, V.I., and Kustov, L.M., Catal. Ind., 2015, no. 7, pp. 60–63.CrossRefGoogle Scholar
  7. 7.
    Hiyoshi, N., Rode, C.V., Sato, O., and Shirai, M., J. Japan Petroleum Inst., 2004, vol. 47 (6), pp. 410–411.CrossRefGoogle Scholar
  8. 8.
    Nunez, S., Montesinos-Castellanos, A., Zepeda, T.A., and los Reyes, J.A., Mater. Res. Innovations, 2008, vol. 12, no. 1, pp. 55–59.CrossRefGoogle Scholar
  9. 9.
    Sapre, A.V. and Gates, B.C., Ind. Eng. Chem. Process Des. Dev., 1981, vol. 20, no. 1, pp. 68–73.CrossRefGoogle Scholar
  10. 10.
    Toppinen, S., Rantakyla, T.K., Salmi, T., and Aittama, J., Ind. Eng. Chem. Res., 1996, vol. 35, pp. 1824–1833.CrossRefGoogle Scholar
  11. 11.
    Lindfors, L.P. and Salmi, T., Ind. Eng. Chem. Res., 1993, vol. 32, pp. 34–42.CrossRefGoogle Scholar
  12. 12.
    Tsukinoki, T., Kanda, T., Liu, G.B., Tsuzuki, H., and Tashiro, M., Tetrahedron Lett., 2000, vol. 41, pp. 5865–5868.CrossRefGoogle Scholar
  13. 13.
    Lu, L., Rong, Z., Du, W., Ma, S., and Hu, S., Chem-CatChem., 2009, vol. 1, pp. 369–371.Google Scholar
  14. 14.
    Ortega-Domínguez, R.A., Vargas-Villagrán, H., Peñaloza-Orta, C., Saavedra-Rubio, K., Bokhimi, X., and Klimova, T.E., Fuel, 2017, vol. 198, pp. 110–122.CrossRefGoogle Scholar
  15. 15.
    Gregg, S.J., Sing, K.S.W., Adsorption, Surface Area and Porosity, Acad. Press, New York, 1982.Google Scholar
  16. 16.
    Bhagiyalakshmi, M., Park, S.D., Cha, W.S., and Jang, H.T., Appl. Surf. Sci., 2010, vol. 256, pp. 6660–6666.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. M. Chernova
    • 1
  • P. P. Minayev
    • 1
  • Ye. A. Martynenko
    • 1
  • Al. A. Pimerzin
    • 1
  • Yu. V. Yeremina
    • 1
  • S. P. Verevkin
    • 1
  • A. A. Pimerzin
    • 1
    Email author
  1. 1.Samara State Technical UniversitySamaraRussia

Personalised recommendations