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Russian Journal of Applied Chemistry

, Volume 91, Issue 10, pp 1671–1679 | Cite as

Detection of Carbon Monoxide in Humid Air with Double-Layer Structures Based on Semiconducting Metal Oxides and Silicalite

  • D. G. Gulevich
  • A. V. Marikutsa
  • M. N. RumyantsevaEmail author
  • P. B. Fabrichnyi
  • T. B. Shatalova
  • A. M. Gas’kov
Sorption and Ion Exchange Processes
  • 6 Downloads

Abstract

Double-layer structures based on gas-sensitive semiconducting metal oxides and silicalite-1 were tested in detection of carbon monoxide in humid air. Pure tin dioxide and that modified with antimony and palladium served as materials of the sensitive layer. Upon deposition of a silicalite-1 layer on SnO2 and SnO2/PdOx, the signal for CO in dry air at room measurement temperature (T = 25°C) grows, but an increase in the air humidity results in that the sensor sensitivity fully disappears. Raising the measurement temperature to 100°C makes weaker the adverse effect of the humidity. The double-layer structure containing the SnO2(Sb)/PdOx nanocomposite is characterized by the most stable sensor signal that is independent of the air humidity within the range RH = 4‒65%.

Keywords

tin dioxide silicalite-1 semiconductor gas sensor passive filter carbon monoxide 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • D. G. Gulevich
    • 1
  • A. V. Marikutsa
    • 1
  • M. N. Rumyantseva
    • 1
    Email author
  • P. B. Fabrichnyi
    • 1
  • T. B. Shatalova
    • 1
  • A. M. Gas’kov
    • 1
  1. 1.Lomonosov Moscow State UniversityMoscowRussia

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