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Russian Journal of Applied Chemistry

, Volume 91, Issue 9, pp 1520–1527 | Cite as

Oxidative Desulfurization of Model Diesel Fuel by Vanadium Granular-Shape Mesoporous (V/GMS) Silica System as Nanocatalyst

  • Razieh Fazaeli
  • Hamid Aliyan
  • Raziyeh Ghanbari
Catalysis
  • 2 Downloads

Abstract

The performance of V-containing granular-shape mesoporous (V/GSM) silica systems in oxidative desulfurization of model diesel fuel was studied. FTIR, XRD, SEM, TEM, N2 adsorption-desorption, UV-Vis, and NH3-TPD techniques were used to analyze the surface properties of the functionalized catalyst. The mesostructure of silica remains intact after vanadium modifications as shown by XRD and adsorption-desorption analysis, while spectroscopy indicates the successful impregnation of neat vanadium oxide inside the porous silica support. The oxidation desulfurization of model diesel fuel was effectively catalyzed by this catalyst and the highest activity was shown by 4.8% V/GSM catalyst. Compared with their conventional V/MCF and V/MCM-41 counterparts, SSM-supported vanadium catalysts showed much higher activity. This may be associated with the higher reducibility and better diffusion of reactants and products in V/MCF and V/MCM-41catalysts.

Keywords

K2FeO4 SO42–/MCM-41 S2O82–/MCM-41 oxidation desulfurization solid superacid 

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References

  1. 1.
    Ishihara, A., Wang, D., and Dumeignil, F., Appl. Catal. A: Gen., 2005, vol. 279, pp. 279–287.CrossRefGoogle Scholar
  2. 2.
    Hernández-Maldonado, A.J., Yang, F.H., Qi, Gongshin, and Yang, R.T., Appl. Catal. B: Env., vol. 56, 2005, pp. 111–126.Google Scholar
  3. 3.
    Xiao, J., Zhang, Y., Zhong, Q., Li, F., Huang, J., and Wang, B., Energy Fuels, 2016, vol. 30, pp. 3385–3391.CrossRefGoogle Scholar
  4. 4.
    Thaligari, S.K., Gupta, S., Srivastava Chandra, V., and Prasad, B., Energy Fuels, 2016, vol. 30, pp. 6161–6168.CrossRefGoogle Scholar
  5. 5.
    Timko, M.T., Schmois, E., Patwardhan, P., Kida, Y., Class, C.A., Green, W.H., Nelson, R.K., and Reddy, C.M., Energy Fuels, 2014, vol. 28, pp. 2977–2983.CrossRefGoogle Scholar
  6. 6.
    Wang, S.-Q., Zhou, L., Su, W., Sun, Y., and Zhou, Y., Env. Energy Eng., 2009, vol. 55, pp. 1872–1881.Google Scholar
  7. 7.
    Tidahy, H.L., Siffert, S., Wyrwalski, F., Lamonier, J.F., and Aboukaïs, A., Catal. Today, 2007, vol. 119, pp. 317–320.CrossRefGoogle Scholar
  8. 8.
    Gennequin, C., Lamallem, M., Cousin, R., Siffert, S., Aïssi, F., and Aboukaïs, A., Catal. Today, 2007, vol. 122, pp. 301–306.CrossRefGoogle Scholar
  9. 9.
    Ordonez, S., Bello, L., Sastre, H., Rosal, R., and Diez, F.V., Appl. Catal. B: Env., 2002, vol. 38, pp. 139–149.CrossRefGoogle Scholar
  10. 10.
    Lahousse, C., Bernier, A., Grange, P., Delmon, B., Papaefthimiou, P., Loannides, T., and Verykios, X., J. Catal., 1998, vol. 178, pp. 214–225.CrossRefGoogle Scholar
  11. 11.
    Jones, J. and Ross, J.R.H., Catal. Today, 1997, vol. 35, pp. 97–105.CrossRefGoogle Scholar
  12. 12.
    Krishnamoorthy, S., Baker, J.P., and Amiridis, M.D., Catal. Today, 1998, vol. 40, pp. 39–46.CrossRefGoogle Scholar
  13. 13.
    Delaigle, R., Debecker, D.P., Bertinchamps, F., and Gaigneaux, E.M., Top. Catal., 2009, vol. 52, pp. 501–516.CrossRefGoogle Scholar
  14. 14.
    Bertinchamps, F., Treinen, M., Eloy, P., Dos Santos, A.M., Mestdagh, M.M., and Gaigneaux, E.M., Appl. Catal. B: Environ., 2007, vol. 70, pp. 360–369.CrossRefGoogle Scholar
  15. 15.
    Cavani, F., Ballarini, N., and Cericola, A., Catal. Today, 2007, vol. 127, pp. 113–131.CrossRefGoogle Scholar
  16. 16.
    Ying, F., Li, J., Huang, C., Weng, W., and Wan, H., Catal. Lett., 2007, vol. 115, pp. 137–142.CrossRefGoogle Scholar
  17. 17.
    Piumetti, M., Bonelli, B., Armandi, M., Gaberova, L., Casale, S., Massiani, P., and Garrone, E., Micropor. Mesopor. Mater., 2010, vol. 133, pp. 36–44.CrossRefGoogle Scholar
  18. 18.
    Piumetti, M., Bonelli, B., Massiani, P., Millot, Y., Dzwigaj, S., Armandi, M., Gaberova, L., and Garrone, E., Micropor. Mesopor. Mater., 2011, vol. 142, pp. 45–54.CrossRefGoogle Scholar
  19. 19.
    Gao, F., Zhang, Y., Wan, H., Kong, Y., Wu, X., Dong, L., Li, B., and Chen, Yi, Micropor. Mesopor. Mater., 2008, vol. 110, pp. 508–516.CrossRefGoogle Scholar
  20. 20.
    Du, L., Song, H., and Liao, S., Appl. Sur. Sci., 2009, vol. 255, pp. 9365–9370.CrossRefGoogle Scholar
  21. 21.
    Cavani, F., Ballarini, N., and Cericola, A., Catal. Today, 2007, vol. 127, pp. 113–131.CrossRefGoogle Scholar
  22. 22.
    Ying, F., Li, J., Huang, C., Weng, W., and Wan, H., Catal. Lett., 2007, vol. 115, pp. 137–142.CrossRefGoogle Scholar
  23. 23.
    Piumetti, M., Bonelli, B., Armandi, M., Gaberova, L., Casale, S., Massiani, P., Garrone, E., Micropor. Mesopor. Mater., 2010, vol. 133, pp. 36–44.CrossRefGoogle Scholar
  24. 24.
    Piumetti, M., Bonelli, B., Massiani, P., Millot, Y., Dzwigaj, S., Armandi, M., Gaberova, L., and Garrone, E., Micropor. Mesopor. Mater., 2011, vol. 142, pp. 45–54.CrossRefGoogle Scholar
  25. 25.
    Liu, Y.M., Cao, Y., Zhu, K.K., Yan, S.R., Dai, W.L., He, H.Y., and Fan, K.N., J. Catal., 2004, vol. 224, pp. 417–428.CrossRefGoogle Scholar
  26. 26.
    Fazaeli, R., Aliyan, H., Moghadam, M., and Masoudinia, M., J. Mol. Catal. A: Chem., 2013, vols. 374–375, pp. 46–52.CrossRefGoogle Scholar
  27. 27.
    Fazaeli, R. and Aliyan, H., Sol-Gel. Sci. Technol., 2015, vol. 76, pp. 456–464.CrossRefGoogle Scholar
  28. 28.
    Liu, Y.-M., Feng, W.-L., Li, T.-C., He, H.-Y., Dai, W.-L., Huang, W., Cao, Y., and Fan, K.-N., J. Catal., 2006, vol. 239, pp. 125–136.CrossRefGoogle Scholar
  29. 29.
    Catana, G., Rao, R.R., Weckhuysen, B.M., Van Der Voort, P., Vansant, E., and Schoonheydt, R.A., J. Phys. Chem., 1998, vol. 102, pp. 8005–8012.CrossRefGoogle Scholar
  30. 30.
    Selvam, P. and Dapurkar, S.E., J. Catal. 229, 2005, pp. 64–71.Google Scholar
  31. 31.
    Centi, G., Perathoner, S., Trifiro, F., Aboukais, A., and Mguelton, Aissi, F., J. Phys. Chem., 1992, vol. 96, pp. 2617–2629.CrossRefGoogle Scholar
  32. 32.
    Sakthivel, A., Dapurkar, S.E., and Selvam, P., Catal. Lett., 2001, vol. 77, pp. 155–164.CrossRefGoogle Scholar
  33. 33.
    Gao, X. and Wachs, I.E., J.Catal., 2000, vol. 192, pp. 18–28.CrossRefGoogle Scholar
  34. 34.
    Niwa, M., Habuta, Y., Okumura, K., and Katada, N., Catal. Today, 2003, vol. 87, pp. 213–218.CrossRefGoogle Scholar
  35. 35.
    Zhang, Y., Wong, W.-T., and Yung, K.-F., Appl. Energy, 2014, vol. 116, pp. 191–198.CrossRefGoogle Scholar
  36. 36.
    Solsona, B., Nieto, J.M.L., and Díaz, U., Microporous Mesoporous Mater., 2006, vol. 94, pp. 339–347.CrossRefGoogle Scholar
  37. 37.
    Chunguang, L., Changxi, M., Yingying, N., Yinghong, Y., Songyuan, G., Weimin, Y., Weiming, H., and Zi, G., Chin. J. Catal., 2010, vol. 31, pp. 993–998.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Razieh Fazaeli
    • 1
  • Hamid Aliyan
    • 1
  • Raziyeh Ghanbari
    • 1
  1. 1.Department of Chemistry, Shahreza BranchIslamic Azad UniversityShahrezaIran

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