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Russian Journal of Applied Chemistry

, Volume 91, Issue 9, pp 1451–1459 | Cite as

Frost-Resistant Polyurethane-Urea Materials Based on Oligoethers

  • V. Yu. Senichev
  • M. A. Makarova
  • A. V. Savchuk
Macromolecular Compounds and Polymeric Materials
  • 4 Downloads

Abstract

Physicomechanical behavior of cross-linked segmented polyester urethane ureas with poly(tetramethylene oxide) segments of varied molecular mass, plasticized with di-(2-ethylhexyl) cebacate, was considered. Data on how the structure of flexible and rigid segments affects the physicomechanical properties of the plasticized material, including those at low temperatures, are presented. Ways were determined for obtaining the optimal hybrid structure of the polymers under study for developing materials with enhanced frost resistance.

Keywords

polyurethane ureas plasticization frost-resistance elastomers 

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References

  1. 1.
    Szycher, M., Szycher’s Handbook of Polyurethanes, Boca Raton: CRC Press, 2013, 2nd ed.Google Scholar
  2. 2.
    Polyurethane, Zafar, F. and Sharmin, E., Eds., Rijeka: InTech, 2012.Google Scholar
  3. 3.
    Prisakariu, C., Polyurethane Elastomers, From Mor phology to Mechanical Aspects, Wien: Springer, 2011.CrossRefGoogle Scholar
  4. 4.
    Yilgor, I., Yilgor, E., and Wilkes, G.L., Polymer, 2015, vol. 58, no. 1, pp. A1–A36.CrossRefGoogle Scholar
  5. 5.
    Alifanov, E.V., Chaikun, A.M., Venediktova, M.A., and Naumov, I.S., Aviats. Mater. Tekhnol., 2015, no. 2, pp. 51–55.Google Scholar
  6. 6.
    Rostiashvili, V.G., Irzhak, V.I., and Rozenberg, B.A., Steklovanie polimerov (Vitrification of Polymers), Leningrad: Khimiya, 1987.Google Scholar
  7. 7.
    Tereshatov, V.V., Makarova, M.A., Strelnikov, V.N., and Volkova, E.R., Russ. J. Appl. Chem., 2010, vol. 83, no. 8, pp. 1345–1351.CrossRefGoogle Scholar
  8. 8.
    Makarova, M.A., Tereshatov, V.V., Vnutskikh, Zh.A., Senichev, V.Yu., Volkova, E.R., Slobodinyuk, A.I., and Kisel’kov, D.M., Fiziko-khimiya Polimerov: Sintez, Svoistva i Primenenie: Sbornik nauchnykh trudov (Physical Chemistry of Polymers: Synthesis, Properties, and Applications: Coll. of Sci. Works), Tver: Tver. Gos. Univ., 2015, issue 21, pp. 227–231.Google Scholar
  9. 9.
    Strel’nikov, V.N., Makarova, M.A., Senichev, V.Yu., Kuchin, A.V., and Sitnikov, P.A., Fiziko-khimiya polimerov: Sintez, svoistva i primenenie (Physical Chemistry of Polymers: Synthesis, Properties, and Applications), Tver: Tver. Gos. Univ., 2014, issue 20, pp. 232–234.Google Scholar
  10. 10.
    Tereshatov, V.V., Vnutskikh, Z.A., Slobodinyuk, A.I., Makarova, M.A., and Senichev, V.Yu., J. Elastomers Plast., 2016, vol. 48, no. 4, pp. 289–304.CrossRefGoogle Scholar
  11. 11.
    Burel, F., Feldman, A., and Bunel, C., Polymer, 2005, vol. 46, no. 1, pp. 15–25.CrossRefGoogle Scholar
  12. 12.
    Handbook of Plasticizers, Wypych, Ed., Toronto: ChemTec Publ., 2017, 3rd ed.Google Scholar
  13. 13.
    Yeh, F., Hsiao, B.S., Sauer, B.B., Michel, S., and Siesler, H.W., Macromolecules, 2003, vol. 36, no. 6, pp. 1940–1954.CrossRefGoogle Scholar
  14. 14.
    Brunette, C.M., Hsu, S.L., and MacKnight, W.J., Macromolecules, 1982, vol. 15, no. 1, pp. 71–77.CrossRefGoogle Scholar
  15. 15.
    Ning, L., De-Ning, W., and Sheng-Kang, Y., Macromolecules, 1997, vol. 30, no. 15, pp. 4405–4409.CrossRefGoogle Scholar
  16. 16.
    Lipatov, Yu.S., Nesterov, A.E., Gritsenko, T.M., and Veselovskii, R.A., Spravochnik po khimii polimerov (Handbook of Polymer Chemistry), Kiev: Naukova Dumka, 1971.Google Scholar
  17. 17.
    Handbook of Solvents, vol. 1, Properties, Wypych, Ed., Toronto: ChemTec Publ., 2014, 2nd ed.Google Scholar
  18. 18.
    Askadskii, A.A. and Matveev, Yu.I., Khimicheskoe stroenie i fizicheskie svoistva polimerov (Chemical Structure and Physical Properties of Polymers), Moscow: Khimiya, 1983.Google Scholar
  19. 19.
    Christenson, E.M., Anderson, J.M., Hiltner, A., and Baer, E., Polymer, 2005, vol. 46, no. 25, pp. 11744–11754.CrossRefGoogle Scholar
  20. 20.
    Tereshatov, V.V., Makarova, M.A., Senichev, V.Yu., Volkova, E.R., Vnutskikh, Zh.A., and Slobodinyuk, A.I., Colloid Polym. Sci., 2015, vol. 293, no. 25, pp. 153–164.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. Yu. Senichev
    • 1
  • M. A. Makarova
    • 1
  • A. V. Savchuk
    • 1
  1. 1.Institute of Technical ChemistryPermRussia

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