Russian Journal of Applied Chemistry

, Volume 90, Issue 12, pp 1931–1938 | Cite as

Isomerization of n-Heptane on Platinum-Zeolite Catalysts in the Presence of Cyclohexane and Benzene

  • E. A. Belopukhov
  • I. M. Kalashnikov
  • M. D. Smolikov
  • V. A. Shkurenok
  • D. I. Kir’yanov
  • A. S. Belyi
Catalysis

Abstract

Effect of cyclohexane and benzene on the isomerization of n-heptane on Pt/BEA-Al2O3 and Pt/MORAl2O3 catalysts was studied. In the presence of catalysts with platinum deposited from a [Pt(NH3)4]Cl2 solution, cyclohexane and benzene inhibit the conversion of n-heptane. At the same time, the presence of cycloalkanes and aromatic hydrocarbons leads to an increase in the isomerization selectivity due to the suppression of side reactions of hydrocracking. Samples based on the BEA zeolite were found to be more active as compared with similar samples based on mordenite.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. A. Belopukhov
    • 1
    • 2
  • I. M. Kalashnikov
    • 1
    • 2
  • M. D. Smolikov
    • 1
    • 2
  • V. A. Shkurenok
    • 1
  • D. I. Kir’yanov
    • 1
  • A. S. Belyi
    • 1
    • 2
  1. 1.Institute of Hydrocarbons Processing, Siberian BranchRussian Academy of SciencesOmskRussia
  2. 2.Omsk State Technical UniversityOmsk, RussiaRussia

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