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Russian Journal of General Chemistry

, Volume 89, Issue 8, pp 1662–1666 | Cite as

Structural Features and Electrical Properties of Chlorine-Substituted Proton Conductors Ba4In2+2xZr2−2xO11−x

  • N. A. TarasovaEmail author
  • A. O. Galisheva
  • I. E. Animitsa
Article

Abstract

Chlorine-substituted perovskite Ba3.95In2Zr2O10.9Cl0.1 was synthesized for the first time, and its single-phase nature was confirmed by X-ray diffraction method. The resultant perovskite has a cubic structure and is a proton conductor at T < 650°C and p(H2O) = 2×10−2 atm. Doping with chlorine was shown to increase the oxygen-ion and proton conductivities.

Keywords

perovskite brownmillerite anion substitution ionic conductivity 

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Notes

Funding

This study was presented orally at the All-Russian Conference with international participation “Solid State Chemistry and Functional Materials” (St. Petersburg, May 21–27, 2018).

This study was financially supported by the Ministry of Education and Science of the Russian Federation (state assignment no. 4.2288.2017) and by the Government of the Russian Federation (Resolution no. 211, agreement no. 02.A03.21.0006).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • N. A. Tarasova
    • 1
    Email author
  • A. O. Galisheva
    • 1
  • I. E. Animitsa
    • 1
  1. 1.Yeltsin Ural Federal UniversityYekaterinburgRussia

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