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Russian Journal of General Chemistry

, Volume 89, Issue 8, pp 1564–1569 | Cite as

N-(2,3-Dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide: Hydrogen Bonds in Crystal and Solution

  • I. V. SterkhovaEmail author
  • I. M. Lazarev
  • B. A. Shainyan
Article
  • 6 Downloads

Abstract

The structure of N-(2,3-dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide and its dimers has been studied in the crystal, solution, and gas phase by means of IR spectroscopy and quantum chemical simulation at the DFT level. The obtained data have been compared to the data of X-ray diffraction analysis.

Keywords

hydrogen bonds IR spectroscopy DFT simulation 

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Notes

Acknowledgments

The authors are thankful to V.V. Astakhova and M.Yu. Moskalik for providing the sample of amide 1 for spectroscopy studies. The major results were obtained using the equipment of the Baikal Analytical Center for Collective Usage of Siberian Branch of Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. V. Sterkhova
    • 1
    Email author
  • I. M. Lazarev
    • 1
  • B. A. Shainyan
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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